Anisotropies in the electrical properties of rod-like aggregates of liquid crystalline phthalocyanines: Direct current conductivities and field-effect mobilities

The direct current (dc) conductivities and organic field-effect transistor (OFET) characteristics of a class of octa-substituted liquid crystalline (discotic mesophase) phthalocyanines (Pcs) are discussed. These molecules self-organize into columnar aggregates with large coherence lengths (up to app...

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Veröffentlicht in:Journal of materials research 2004-07, Vol.19 (7), p.2087-2099
Hauptverfasser: Donley, Carrie L., Zangmeister, R.A.P., Xia, Wei, Minch, Britt, Drager, Anthony, Cherian, Samir K., LaRussa, Lynn, Kippelen, Bernard, Domercq, Benoit, Mathine, David L., O’Brien, David F., Armstrong, Neal R.
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container_end_page 2099
container_issue 7
container_start_page 2087
container_title Journal of materials research
container_volume 19
creator Donley, Carrie L.
Zangmeister, R.A.P.
Xia, Wei
Minch, Britt
Drager, Anthony
Cherian, Samir K.
LaRussa, Lynn
Kippelen, Bernard
Domercq, Benoit
Mathine, David L.
O’Brien, David F.
Armstrong, Neal R.
description The direct current (dc) conductivities and organic field-effect transistor (OFET) characteristics of a class of octa-substituted liquid crystalline (discotic mesophase) phthalocyanines (Pcs) are discussed. These molecules self-organize into columnar aggregates with large coherence lengths (up to approximately 300 nm). Langmuir–Blodgett films of these molecules were horizontally transferred to either interdigitated microelectrodes (IME) or OFET substrates, so that current flow could be measured either parallel or perpendicular to the column axis. Twenty-eight bilayer films of these Pcs on the IME substrates showed anisotropies in dc conductivity up to 50:1, whereas similar Pc films showed anisotropies in field effect mobilities of approximately 10:1, for a variety of W/L ratios (source/drain dimensions and spacing). Field-effect mobilities of 1 to 5 × 10-6 cm2·V-1·s-1 were determined from OFET measurements, along the Pc column axis, whereas charge mobilities measured from the space charge limited current regime on the IME substrates were in the range of 10-4 cm2·V-1·s-1. Conductive tip atomic force microscopy measurements on the apprximately 500-nm length scale showed that the conductivity anisotropy can be as high as 1000:1 when the Pc columns are intimately contacted to an adjacent Au bond pad.
doi_str_mv 10.1557/JMR.2004.0278
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subjects Electrical properties
Organic
Self-assembly
title Anisotropies in the electrical properties of rod-like aggregates of liquid crystalline phthalocyanines: Direct current conductivities and field-effect mobilities
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