SrCl2·6H2O: An Alkaline-Earth-Metal Chloride Hexahydrate as Deep-Ultraviolet Nonlinear-Optical Crystal with the {[Sr(H2O)6]2+}∞ Cationic Framework

SrCl2·6H2O: An Alkaline-Earth-Metal Chloride Hexahydrate as Deep-Ultraviolet Nonlinear-Optical Crystal with the {[Sr(H2O)6]2+}∞ Cationic Framework

Exploring deep-ultraviolet (DUV) nonlinear-optical (NLO) materials is significant for the conversion of high-frequency laser. Herein, two alkali-earth-metal halide hexahydrates, SrX2·6H2O (X = Cl, Br), were obtained, and the centimeter-sized single crystals of SrCl2·6H2O were grown by a slow evapora...

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Veröffentlicht in:Inorganic chemistry 2023-07, Vol.62 (27), p.10523-10527
Hauptverfasser: Xu, Wei, Tang, Ru-Ling, Wei, Yu-Long, Wang, Jin-Ming, Zhang, Yu-Qing, Liu, Wenlong, Guo, Sheng-Ping
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container_end_page 10527
container_issue 27
container_start_page 10523
container_title Inorganic chemistry
container_volume 62
creator Xu, Wei
Tang, Ru-Ling
Wei, Yu-Long
Wang, Jin-Ming
Zhang, Yu-Qing
Liu, Wenlong
Guo, Sheng-Ping
description Exploring deep-ultraviolet (DUV) nonlinear-optical (NLO) materials is significant for the conversion of high-frequency laser. Herein, two alkali-earth-metal halide hexahydrates, SrX2·6H2O (X = Cl, Br), were obtained, and the centimeter-sized single crystals of SrCl2·6H2O were grown by a slow evaporation method. Both of them crystallize in the trigonal space group P321, and their crystal structures show {[Sr­(H2O)6]2+}∞ cationic chains, with isolated Cl– or Br– anions interspersed between the chains. SrCl2·6H2O exhibits a moderate second-harmonic-generation response (0.4 × KDP) at 1064 nm and can realize phase matching. Importantly, SrCl2·6H2O has a short ultraviolet cutoff edge (
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title SrCl2·6H2O: An Alkaline-Earth-Metal Chloride Hexahydrate as Deep-Ultraviolet Nonlinear-Optical Crystal with the {[Sr(H2O)6]2+}∞ Cationic Framework
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