Manganese catalysed dehydrogenative synthesis of polyureas from diformamide and diamines

We report here the synthesis of polyureas from the dehydrogenative coupling of diamines and diformamides. The reaction is catalysed by a manganese pincer complex and releases H 2 gas as the only by-product making the process atom-economic and sustainable. The reported method is greener in comparison...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Catalysis science & technology 2023-06, Vol.13 (12), p.3551-3557
Hauptverfasser:	McLuskie, Angus, Brodie, Claire N, Tricarico, Michele, Gao, Chang, Peters, Gavin, Naden, Aaron B, Mackay, C. Logan, Tan, Jin-Chong, Kumar, Amit
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Chemistry Dehydrogenation Diamines Diisocyanates Isocyanates Manganese Mechanical properties Phosgene Polyureas
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!