In situ ionic/electric conductivity measurement of La0.55Li0.35TiO3 ceramic at different Li insertion levels
The electrical conductivities of solid La0.55Li0.35TiO3 electrolytes at different Li intercalation levels were measured, in situ, using a special cell and electrode design. The relative changes in electrical conductivities of La0.55Li0.35TiO3 at different Li insertion levels in liquid electrolytes w...
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| Veröffentlicht in: | Journal of the Electrochemical Society 2004, Vol.151 (8), p.A1196-A1201 |
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| container_end_page | A1201 |
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| container_issue | 8 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 151 |
| creator | CHUNSHENG WANG PATIL, Prashanth APPLEBY, A. John LITTLE, Frank E KESMEZ, Mehmet COCKE, David L |
| description | The electrical conductivities of solid La0.55Li0.35TiO3 electrolytes at different Li intercalation levels were measured, in situ, using a special cell and electrode design. The relative changes in electrical conductivities of La0.55Li0.35TiO3 at different Li insertion levels in liquid electrolytes were monitored by the voltage across the La0.55Li0.35+xTiO3 powder disk electrode sandwiched between two nickel screens and charged only on one nickel screen. The real electrical conductivities of the La0.55Li0.35+xTiO3 ceramic at different Li insertion levels x without influence of high-ion-conductivity liquid electrolytes was measured by electrochemical impedance spectroscopy using sintered La0.55Li0.35+xTiO3 disk electrodes with Au coating on both sides. Lithium was electrochemically inserted into La0.55Li0.35TiO3 when the Au coated disk electrodes were immersed into liquid electrolytes with the cell inverted. The impedances of La0.55Lo0.35+xTiO3 electrodes were then measured with the disk electrode suspended above the liquid electrolyte with the cell upright. |
| doi_str_mv | 10.1149/1.1767157 |
| format | Article |
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John ; LITTLE, Frank E ; KESMEZ, Mehmet ; COCKE, David L</creator><creatorcontrib>CHUNSHENG WANG ; PATIL, Prashanth ; APPLEBY, A. John ; LITTLE, Frank E ; KESMEZ, Mehmet ; COCKE, David L</creatorcontrib><description>The electrical conductivities of solid La0.55Li0.35TiO3 electrolytes at different Li intercalation levels were measured, in situ, using a special cell and electrode design. The relative changes in electrical conductivities of La0.55Li0.35TiO3 at different Li insertion levels in liquid electrolytes were monitored by the voltage across the La0.55Li0.35+xTiO3 powder disk electrode sandwiched between two nickel screens and charged only on one nickel screen. The real electrical conductivities of the La0.55Li0.35+xTiO3 ceramic at different Li insertion levels x without influence of high-ion-conductivity liquid electrolytes was measured by electrochemical impedance spectroscopy using sintered La0.55Li0.35+xTiO3 disk electrodes with Au coating on both sides. Lithium was electrochemically inserted into La0.55Li0.35TiO3 when the Au coated disk electrodes were immersed into liquid electrolytes with the cell inverted. The impedances of La0.55Lo0.35+xTiO3 electrodes were then measured with the disk electrode suspended above the liquid electrolyte with the cell upright.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.1767157</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>Applied sciences ; Direct energy conversion and energy accumulation ; Electrical engineering. 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The real electrical conductivities of the La0.55Li0.35+xTiO3 ceramic at different Li insertion levels x without influence of high-ion-conductivity liquid electrolytes was measured by electrochemical impedance spectroscopy using sintered La0.55Li0.35+xTiO3 disk electrodes with Au coating on both sides. Lithium was electrochemically inserted into La0.55Li0.35TiO3 when the Au coated disk electrodes were immersed into liquid electrolytes with the cell inverted. The impedances of La0.55Lo0.35+xTiO3 electrodes were then measured with the disk electrode suspended above the liquid electrolyte with the cell upright.</description><subject>Applied sciences</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Exact sciences and technology</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNotj8tqwzAUREVpoWnaRf9Am3ZnR1eypGhZQh8BQzbZG1m-BhXZTiU5kL-vS7MaBs4cGEKegZUAldlACVppkPqGrMBUstAAcEtWjIEoKiXhnjyk9L1U2FZ6RcJ-pMnnmfpp9G6DAV2O3lE3jd3ssj_7fKED2jRHHHDMdOppbVkpZe1ZKeTRHwR1GO2wjGymne97jH9g7akfE8a8mGnAM4b0SO56GxI-XXNNjh_vx91XUR8-97u3ujhBpXLRu5az1okKuLJbDcJYMGhsx7WqWitdZxUyIx3vgDOhl1uKOxDQdp1pt2JNXv-1pzj9zJhyM_jkMAQ74jSnhm_58l2ZBXy5gjY5G_poR-dTc4p-sPHSgGKMgzbiF2gIZnA</recordid><startdate>2004</startdate><enddate>2004</enddate><creator>CHUNSHENG WANG</creator><creator>PATIL, Prashanth</creator><creator>APPLEBY, A. 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Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Exact sciences and technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>CHUNSHENG WANG</creatorcontrib><creatorcontrib>PATIL, Prashanth</creatorcontrib><creatorcontrib>APPLEBY, A. 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John</au><au>LITTLE, Frank E</au><au>KESMEZ, Mehmet</au><au>COCKE, David L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ ionic/electric conductivity measurement of La0.55Li0.35TiO3 ceramic at different Li insertion levels</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>2004</date><risdate>2004</risdate><volume>151</volume><issue>8</issue><spage>A1196</spage><epage>A1201</epage><pages>A1196-A1201</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>The electrical conductivities of solid La0.55Li0.35TiO3 electrolytes at different Li intercalation levels were measured, in situ, using a special cell and electrode design. The relative changes in electrical conductivities of La0.55Li0.35TiO3 at different Li insertion levels in liquid electrolytes were monitored by the voltage across the La0.55Li0.35+xTiO3 powder disk electrode sandwiched between two nickel screens and charged only on one nickel screen. The real electrical conductivities of the La0.55Li0.35+xTiO3 ceramic at different Li insertion levels x without influence of high-ion-conductivity liquid electrolytes was measured by electrochemical impedance spectroscopy using sintered La0.55Li0.35+xTiO3 disk electrodes with Au coating on both sides. Lithium was electrochemically inserted into La0.55Li0.35TiO3 when the Au coated disk electrodes were immersed into liquid electrolytes with the cell inverted. The impedances of La0.55Lo0.35+xTiO3 electrodes were then measured with the disk electrode suspended above the liquid electrolyte with the cell upright.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.1767157</doi></addata></record> |
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| language | eng |
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| source | Institute of Physics Journals |
| subjects | Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology |
| title | In situ ionic/electric conductivity measurement of La0.55Li0.35TiO3 ceramic at different Li insertion levels |
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