Silver‐catalyzed Regioselective Synthesis of N‐aryl‐1H‐pyrazolyl‐substituted Benzenesulfonamides from Ynamides and Pyrazoles
Silver‐catalyzed N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were obtained regioselectively from ynamides and pyrazoles. In this intermolecular organic transformation, several substituted benzenesulfonamides were obtained in good to excellent yields by forming a new C−N bond under...
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| Veröffentlicht in: | Chemistry, an Asian journal an Asian journal, 2023-08, Vol.18 (15), p.e202300346-n/a |
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| container_title | Chemistry, an Asian journal |
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| creator | Karunakar, Galla V. Raju, Chittala Emmaniel Himaja, Karra Sai Bhavani Nagasri Kumar, Perla Bharath Sridhar, Balasubramanian |
| description | Silver‐catalyzed N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were obtained regioselectively from ynamides and pyrazoles. In this intermolecular organic transformation, several substituted benzenesulfonamides were obtained in good to excellent yields by forming a new C−N bond under mild reaction conditions.
Silver‐catalyzed regioselective synthesis of N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were achieved from ynamides and pyrazoles. Benzenesulfonamides were prepared with good to excellent yields from substituted pyrazoles via silver‐catalyzed intermolecular organic transformations, and one new C−N bond was formed under mild reaction condition. |
| doi_str_mv | 10.1002/asia.202300346 |
| format | Article |
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Silver‐catalyzed regioselective synthesis of N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were achieved from ynamides and pyrazoles. Benzenesulfonamides were prepared with good to excellent yields from substituted pyrazoles via silver‐catalyzed intermolecular organic transformations, and one new C−N bond was formed under mild reaction condition.</description><identifier>ISSN: 1861-4728</identifier><identifier>EISSN: 1861-471X</identifier><identifier>DOI: 10.1002/asia.202300346</identifier><identifier>PMID: 37340707</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Aromatic compounds ; Chemical synthesis ; Chemistry ; C−N bond formation ; Homogeneous silver-catalysis ; Regioselectivity ; substituted pyrazoles ; Substitutes ; ynamides</subject><ispartof>Chemistry, an Asian journal, 2023-08, Vol.18 (15), p.e202300346-n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><rights>2023 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-8971-8550</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fasia.202300346$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fasia.202300346$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37340707$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Karunakar, Galla V.</creatorcontrib><creatorcontrib>Raju, Chittala Emmaniel</creatorcontrib><creatorcontrib>Himaja, Karra Sai Bhavani Nagasri</creatorcontrib><creatorcontrib>Kumar, Perla Bharath</creatorcontrib><creatorcontrib>Sridhar, Balasubramanian</creatorcontrib><title>Silver‐catalyzed Regioselective Synthesis of N‐aryl‐1H‐pyrazolyl‐substituted Benzenesulfonamides from Ynamides and Pyrazoles</title><title>Chemistry, an Asian journal</title><addtitle>Chem Asian J</addtitle><description>Silver‐catalyzed N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were obtained regioselectively from ynamides and pyrazoles. In this intermolecular organic transformation, several substituted benzenesulfonamides were obtained in good to excellent yields by forming a new C−N bond under mild reaction conditions.
Silver‐catalyzed regioselective synthesis of N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were achieved from ynamides and pyrazoles. Benzenesulfonamides were prepared with good to excellent yields from substituted pyrazoles via silver‐catalyzed intermolecular organic transformations, and one new C−N bond was formed under mild reaction condition.</description><subject>Aromatic compounds</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>C−N bond formation</subject><subject>Homogeneous silver-catalysis</subject><subject>Regioselectivity</subject><subject>substituted pyrazoles</subject><subject>Substitutes</subject><subject>ynamides</subject><issn>1861-4728</issn><issn>1861-471X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkTtPwzAUhS0E4lFYGVEkFpaAX_VjLBUvCQGiIMEUOcktGDlJiZOidGJi5jfyS3ApdGDx9bW_e2Sfg9AuwYcEY3pkvDWHFFOGMeNiBW0SJUjMJXlYXe6p2kBb3r9g3KdYq3W0wSTjWGK5iT5G1k2h_nr_zExjXDeDPLqFJ1t5cJA1dgrRqCubZ_DWR9U4ugqkqTsXCjkPy6SrzaxyPwe-TX1jm7YJGsdQzqAE37pxVZrC5uCjcV0V0eNfZ8o8ullMg99Ga2PjPOz81h66Pz25G57Hl9dnF8PBZTyhSotYa9lngvFUaWk4E0IQTbJMahA6_DPPQwWepUynXDJFIBeKZTrNtEo1p5L10MFCd1JXry34Jimsz8A5U0LV-oQqqpjgfTlH9_-hL1Vbl-F1geI8WM6CeA_t_VJtWkCeTGpbBH-SP4cDoBfAm3XQLe8JTub5JfP8kmV-yWB0MVh27BsLMJUv</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Karunakar, Galla V.</creator><creator>Raju, Chittala Emmaniel</creator><creator>Himaja, Karra Sai Bhavani Nagasri</creator><creator>Kumar, Perla Bharath</creator><creator>Sridhar, Balasubramanian</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8971-8550</orcidid></search><sort><creationdate>20230801</creationdate><title>Silver‐catalyzed Regioselective Synthesis of N‐aryl‐1H‐pyrazolyl‐substituted Benzenesulfonamides from Ynamides and Pyrazoles</title><author>Karunakar, Galla V. ; Raju, Chittala Emmaniel ; Himaja, Karra Sai Bhavani Nagasri ; Kumar, Perla Bharath ; Sridhar, Balasubramanian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2896-99753634b897a43666191cc79e69472dde69e4cb39b47381ed683c9bc98b94273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aromatic compounds</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>C−N bond formation</topic><topic>Homogeneous silver-catalysis</topic><topic>Regioselectivity</topic><topic>substituted pyrazoles</topic><topic>Substitutes</topic><topic>ynamides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karunakar, Galla V.</creatorcontrib><creatorcontrib>Raju, Chittala Emmaniel</creatorcontrib><creatorcontrib>Himaja, Karra Sai Bhavani Nagasri</creatorcontrib><creatorcontrib>Kumar, Perla Bharath</creatorcontrib><creatorcontrib>Sridhar, Balasubramanian</creatorcontrib><collection>PubMed</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry, an Asian journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karunakar, Galla V.</au><au>Raju, Chittala Emmaniel</au><au>Himaja, Karra Sai Bhavani Nagasri</au><au>Kumar, Perla Bharath</au><au>Sridhar, Balasubramanian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Silver‐catalyzed Regioselective Synthesis of N‐aryl‐1H‐pyrazolyl‐substituted Benzenesulfonamides from Ynamides and Pyrazoles</atitle><jtitle>Chemistry, an Asian journal</jtitle><addtitle>Chem Asian J</addtitle><date>2023-08-01</date><risdate>2023</risdate><volume>18</volume><issue>15</issue><spage>e202300346</spage><epage>n/a</epage><pages>e202300346-n/a</pages><issn>1861-4728</issn><eissn>1861-471X</eissn><abstract>Silver‐catalyzed N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were obtained regioselectively from ynamides and pyrazoles. In this intermolecular organic transformation, several substituted benzenesulfonamides were obtained in good to excellent yields by forming a new C−N bond under mild reaction conditions.
Silver‐catalyzed regioselective synthesis of N‐aryl‐1H‐pyrazolyl substituted benzenesulfonamide derivatives were achieved from ynamides and pyrazoles. Benzenesulfonamides were prepared with good to excellent yields from substituted pyrazoles via silver‐catalyzed intermolecular organic transformations, and one new C−N bond was formed under mild reaction condition.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>37340707</pmid><doi>10.1002/asia.202300346</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-8971-8550</orcidid></addata></record> |
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| identifier | ISSN: 1861-4728 |
| ispartof | Chemistry, an Asian journal, 2023-08, Vol.18 (15), p.e202300346-n/a |
| issn | 1861-4728 1861-471X |
| language | eng |
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| source | Wiley Online Library - AutoHoldings Journals |
| subjects | Aromatic compounds Chemical synthesis Chemistry C−N bond formation Homogeneous silver-catalysis Regioselectivity substituted pyrazoles Substitutes ynamides |
| title | Silver‐catalyzed Regioselective Synthesis of N‐aryl‐1H‐pyrazolyl‐substituted Benzenesulfonamides from Ynamides and Pyrazoles |
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