An efficient mixed-valence copper pyrazolate catalyst for the conversion of carbon dioxide and epoxides into cyclic carbonates

In this paper, a cyclic (Cu I pz) 3 ·CH 3 CN ( 1 ) precursor and a mixed-valence pentanuclear complex Cu I 3 Cu II 2 (OH)pz 6 ·CH 3 CN ( 2 ) have been synthesized and structurally characterized by single-crystal X-ray diffraction, where pzH = 4-chloro-3,5-diphenylpyrazole. The excellent catalytic ac...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2023-07, Vol.52 (27), p.9275-9281
Hauptverfasser:	Wang, Jian-Ge, Liu, Yang, Liu, Chun-Mei, Chen, Jing-Huo, Yang, Guang
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Carbonates Catalytic activity Copper Copper converters Density functional theory Pressure Room temperature Single crystals Steric hindrance
Online-Zugang:	Volltext
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