Advanced Hydrogen‐Storage Materials Based on Sc‐, Ce‐, and Pr‐Doped NaAlH4

The most favorable dopants for solid‐state hydrogen‐storage materials are still considered to be compounds of titanium in spite of intensive research on other catalysts. Here, we show that NaAlH4 doped with ScCl3 is a highly efficient dopant, both with respect to storage capacity and kinetics: 2 mol...

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Veröffentlicht in:	Advanced materials (Weinheim) 2006-05, Vol.18 (9), p.1198-1201
Hauptverfasser:	Bogdanović, B., Felderhoff, M., Pommerin, A., Schüth, F., Spielkamp, N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Hydrogen storage Rare‐earth compounds Reversible storage capacity Transition metals
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description	The most favorable dopants for solid‐state hydrogen‐storage materials are still considered to be compounds of titanium in spite of intensive research on other catalysts. Here, we show that NaAlH4 doped with ScCl3 is a highly efficient dopant, both with respect to storage capacity and kinetics: 2 mol % ScCl3 exhibits a nearly theoretical hydrogen‐storage capacity (4.9 wt %, see graph). Other rare‐earth metal trichlorides are also investigated.
doi_str_mv	10.1002/adma.200501367
format	Article
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subjects	Hydrogen storage Rare‐earth compounds Reversible storage capacity Transition metals
title	Advanced Hydrogen‐Storage Materials Based on Sc‐, Ce‐, and Pr‐Doped NaAlH4
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