Structural verification and new reactivity for Stang's reagent, [PhI(CN)][OTf]

The structure of Stang's reagent [PhI(CN)][OTf] is confirmed by X-ray crystallography and is determined to be best described as an ion-pair in organic solution. It is found to be a strong Lewis acid, but reaction with pyridine ligands gives [Pyr-CN][OTf] salts via oxidation of pyridine giving a...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2023-06, Vol.52 (25), p.8536-8539
Hauptverfasser:	Bennetts, Jason D, Barwise, Lachlan, Sharp-Bucknall, Lachlan, White, Keith F, Hogan, Conor F, Dutton, Jason L
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography Ion pairs Lewis acid Oxidation Polysaccharides Pyridines Reagents
Online-Zugang:	Volltext
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