Modification of ground-state chemical reactivity via light-matter coherence in infrared cavities

Reaction-rate modifications for chemical processes due to strong coupling between reactant molecular vibrations and the cavity vacuum have been reported; however, no currently accepted mechanisms explain these observations. In this work, reaction-rate constants were extracted from evolving cavity tr...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2023-06, Vol.380 (6650), p.1165-1168
Hauptverfasser:	Ahn, Wonmi, Triana, Johan F, Recabal, Felipe, Herrera, Felipe, Simpkins, Blake S
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcoholysis Chemical reactions Cyclohexanol Electromagnetic fields Holes Isocyanates Microcavities Polaritons Strong interactions (field theory)
Online-Zugang:	Volltext
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