Miscibility behavior and hydrogen bonding in blends of poly(vinyl phenyl ketone hydrogenated) and poly(2-ethyl-2-oxazoline)
The miscibility behavior of poly(2‐ethyl‐2‐oxazoline) (PEOx)/poly(vinyl phenyl ketone hydrogenated) (PVPhKH) blends was studied for the entire range of compositions. Differential scanning calorimetry and thermomechanical analysis measurements showed that all the PEOx/PVPhKH blends studied had a sing...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2004-02, Vol.42 (4), p.636-645 |
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| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 42 |
| creator | Maldonado-Santoyo, M. Ortíz-Estrada, C. Luna-Bárcenas, G. Sanchez, I. C. Cesteros, L. C. Katime, I. Nuño-Donlucas, S. M. |
| description | The miscibility behavior of poly(2‐ethyl‐2‐oxazoline) (PEOx)/poly(vinyl phenyl ketone hydrogenated) (PVPhKH) blends was studied for the entire range of compositions. Differential scanning calorimetry and thermomechanical analysis measurements showed that all the PEOx/PVPhKH blends studied had a single glass‐transition temperature (Tg). The natural tendency of PVPhKH to self‐associate through hydrogen bonding was modified by the presence of PEOx. Partial IR spectra of these blends suggested that amide groups in PEOx and hydroxyl groups in PVPhKH interacted through hydrogen bonding. This physical interaction had a positive influence on the phase behavior of PEOx/PVPhKH blends. The Kwei equation for Tg as a function of the blend composition was satisfactorily used to describe the experimental data. Pure‐component pressure–volume–temperature data were also reported for both PEOx and PVPhKH. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 636–645, 2004 |
| doi_str_mv | 10.1002/polb.10758 |
| format | Article |
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C. ; Cesteros, L. C. ; Katime, I. ; Nuño-Donlucas, S. M.</creator><creatorcontrib>Maldonado-Santoyo, M. ; Ortíz-Estrada, C. ; Luna-Bárcenas, G. ; Sanchez, I. C. ; Cesteros, L. C. ; Katime, I. ; Nuño-Donlucas, S. M.</creatorcontrib><description>The miscibility behavior of poly(2‐ethyl‐2‐oxazoline) (PEOx)/poly(vinyl phenyl ketone hydrogenated) (PVPhKH) blends was studied for the entire range of compositions. Differential scanning calorimetry and thermomechanical analysis measurements showed that all the PEOx/PVPhKH blends studied had a single glass‐transition temperature (Tg). The natural tendency of PVPhKH to self‐associate through hydrogen bonding was modified by the presence of PEOx. Partial IR spectra of these blends suggested that amide groups in PEOx and hydroxyl groups in PVPhKH interacted through hydrogen bonding. This physical interaction had a positive influence on the phase behavior of PEOx/PVPhKH blends. The Kwei equation for Tg as a function of the blend composition was satisfactorily used to describe the experimental data. Pure‐component pressure–volume–temperature data were also reported for both PEOx and PVPhKH. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 636–645, 2004</description><identifier>ISSN: 0887-6266</identifier><identifier>EISSN: 1099-0488</identifier><identifier>DOI: 10.1002/polb.10758</identifier><identifier>CODEN: JPLPAY</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Exact sciences and technology ; glass transition ; hydrogen bonding ; infrared spectroscopy ; miscibility ; miscible blends ; Organic polymers ; Physicochemistry of polymers ; poly(vinyl phenyl ketone hydrogenated) ; pressure-volume-temperature properties ; Properties and characterization ; specific interactions ; Thermal and thermodynamic properties</subject><ispartof>Journal of polymer science. 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C.</creatorcontrib><creatorcontrib>Cesteros, L. C.</creatorcontrib><creatorcontrib>Katime, I.</creatorcontrib><creatorcontrib>Nuño-Donlucas, S. M.</creatorcontrib><title>Miscibility behavior and hydrogen bonding in blends of poly(vinyl phenyl ketone hydrogenated) and poly(2-ethyl-2-oxazoline)</title><title>Journal of polymer science. Part B, Polymer physics</title><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><description>The miscibility behavior of poly(2‐ethyl‐2‐oxazoline) (PEOx)/poly(vinyl phenyl ketone hydrogenated) (PVPhKH) blends was studied for the entire range of compositions. Differential scanning calorimetry and thermomechanical analysis measurements showed that all the PEOx/PVPhKH blends studied had a single glass‐transition temperature (Tg). The natural tendency of PVPhKH to self‐associate through hydrogen bonding was modified by the presence of PEOx. Partial IR spectra of these blends suggested that amide groups in PEOx and hydroxyl groups in PVPhKH interacted through hydrogen bonding. This physical interaction had a positive influence on the phase behavior of PEOx/PVPhKH blends. The Kwei equation for Tg as a function of the blend composition was satisfactorily used to describe the experimental data. Pure‐component pressure–volume–temperature data were also reported for both PEOx and PVPhKH. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 636–645, 2004</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>glass transition</subject><subject>hydrogen bonding</subject><subject>infrared spectroscopy</subject><subject>miscibility</subject><subject>miscible blends</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(vinyl phenyl ketone hydrogenated)</subject><subject>pressure-volume-temperature properties</subject><subject>Properties and characterization</subject><subject>specific interactions</subject><subject>Thermal and thermodynamic properties</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp9kM1uEzEUhUcIJEJhwxPMBkSRDLbH458lDRCQUsoCxNLyz53G1LWDPS0deHkmSSk7VvdK_s5n3dM0Twl-RTCmr7c52nkTvbzXLAhWCmEm5f1mgaUUiFPOHzaPav2O8fzWq0Xz-zRUF2yIYZxaCxtzHXJpTfLtZvIln0NqbU4-pPM2zGuE5Gubh3b-aHpxHdIU2-0GduMCxpzgLmZG8Md70R6lCMbNFBFF-cb8yjEkOH7cPBhMrPDkdh41X9-_-7L8gNZnq4_LN2vkOoElYtSSDhTzrhuMEw6ss6C8Aq8sUdSqnnEm7GAll0o6wawZ5qDnnnSG2a47ap4fvNuSf1xBHfXlfDTEaBLkq6qppFzSHs_gywPoSq61wKC3JVyaMmmC9a5fvetX7_ud4We3VlOdiUMxyYX6L9EzRonYceTA_QwRpv8Y9eez9clfNzpkQh3h5i5jyoXmohO9_vZppeXyRL09XUnNuz9D_JwP</recordid><startdate>20040215</startdate><enddate>20040215</enddate><creator>Maldonado-Santoyo, M.</creator><creator>Ortíz-Estrada, C.</creator><creator>Luna-Bárcenas, G.</creator><creator>Sanchez, I. 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M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Miscibility behavior and hydrogen bonding in blends of poly(vinyl phenyl ketone hydrogenated) and poly(2-ethyl-2-oxazoline)</atitle><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><date>2004-02-15</date><risdate>2004</risdate><volume>42</volume><issue>4</issue><spage>636</spage><epage>645</epage><pages>636-645</pages><issn>0887-6266</issn><eissn>1099-0488</eissn><coden>JPLPAY</coden><abstract>The miscibility behavior of poly(2‐ethyl‐2‐oxazoline) (PEOx)/poly(vinyl phenyl ketone hydrogenated) (PVPhKH) blends was studied for the entire range of compositions. Differential scanning calorimetry and thermomechanical analysis measurements showed that all the PEOx/PVPhKH blends studied had a single glass‐transition temperature (Tg). The natural tendency of PVPhKH to self‐associate through hydrogen bonding was modified by the presence of PEOx. Partial IR spectra of these blends suggested that amide groups in PEOx and hydroxyl groups in PVPhKH interacted through hydrogen bonding. This physical interaction had a positive influence on the phase behavior of PEOx/PVPhKH blends. The Kwei equation for Tg as a function of the blend composition was satisfactorily used to describe the experimental data. Pure‐component pressure–volume–temperature data were also reported for both PEOx and PVPhKH. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 636–645, 2004</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/polb.10758</doi><tpages>10</tpages></addata></record> |
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| subjects | Applied sciences Exact sciences and technology glass transition hydrogen bonding infrared spectroscopy miscibility miscible blends Organic polymers Physicochemistry of polymers poly(vinyl phenyl ketone hydrogenated) pressure-volume-temperature properties Properties and characterization specific interactions Thermal and thermodynamic properties |
| title | Miscibility behavior and hydrogen bonding in blends of poly(vinyl phenyl ketone hydrogenated) and poly(2-ethyl-2-oxazoline) |
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