Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation
The kinetic mechanism of structure healing after unloading from large elongation for styrene–butadiene–styrene (SBS) block copolymer materials was investigated by following their residual deformation recovery behaviors upon annealing. A linear relationship was found to exist between the deformation...
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| Veröffentlicht in: | Journal of applied polymer science 2004-05, Vol.92 (4), p.2593-2598 |
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| container_end_page | 2598 |
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| container_title | Journal of applied polymer science |
| container_volume | 92 |
| creator | Wang, You Wang, Binsong Shen, Jingshu |
| description | The kinetic mechanism of structure healing after unloading from large elongation for styrene–butadiene–styrene (SBS) block copolymer materials was investigated by following their residual deformation recovery behaviors upon annealing. A linear relationship was found to exist between the deformation recovery percentage and the logarithm of time at different temperatures, which shed light on the mechanism of structure healing. A modified activation energy model was proposed to describe the kinetics of the process. It was also found that the model agrees well with other SBS structure healing–related experimental data such as the recovery of hardness as well as dynamic mechanical property after large elongation. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2593–2598, 2004 |
| doi_str_mv | 10.1002/app.20235 |
| format | Article |
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A linear relationship was found to exist between the deformation recovery percentage and the logarithm of time at different temperatures, which shed light on the mechanism of structure healing. A modified activation energy model was proposed to describe the kinetics of the process. It was also found that the model agrees well with other SBS structure healing–related experimental data such as the recovery of hardness as well as dynamic mechanical property after large elongation. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2593–2598, 2004</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.20235</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; block copolymers ; Exact sciences and technology ; kinetics (polym.) ; mechanical properties ; Physicochemistry of polymers ; Polymer industry, paints, wood ; strain ; structure healing ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 2004-05, Vol.92 (4), p.2593-2598</ispartof><rights>Copyright © 2004 Wiley Periodicals, Inc.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3665-de5f0da31e52ded74939a718ef2acaa44cb788621174d2a04154bb91622b7c423</citedby><cites>FETCH-LOGICAL-c3665-de5f0da31e52ded74939a718ef2acaa44cb788621174d2a04154bb91622b7c423</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.20235$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.20235$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15610580$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, You</creatorcontrib><creatorcontrib>Wang, Binsong</creatorcontrib><creatorcontrib>Shen, Jingshu</creatorcontrib><title>Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The kinetic mechanism of structure healing after unloading from large elongation for styrene–butadiene–styrene (SBS) block copolymer materials was investigated by following their residual deformation recovery behaviors upon annealing. A linear relationship was found to exist between the deformation recovery percentage and the logarithm of time at different temperatures, which shed light on the mechanism of structure healing. A modified activation energy model was proposed to describe the kinetics of the process. It was also found that the model agrees well with other SBS structure healing–related experimental data such as the recovery of hardness as well as dynamic mechanical property after large elongation. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2593–2598, 2004</description><subject>Applied sciences</subject><subject>block copolymers</subject><subject>Exact sciences and technology</subject><subject>kinetics (polym.)</subject><subject>mechanical properties</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>strain</subject><subject>structure healing</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1kE1v1DAQhiMEEkvhwD_wBSQOaW3HH8mxWtFtpVWpEB9Ha-JMds06cbCzwP573KbACWmkGWme9x3NWxSvGT1nlPILmKZzTnklnxQrRhtdCsXrp8Uq71hZN418XrxI6RuljEmqVsV0M_7ANLsdzC6MJNe8R3JwI87OkgHtHkaXBhJ6kuZ4tPMxItkjeDfuSB8iaX2wB2LDFPxpwEgGmDE68IlAnyfiIe6QoA_jcuJl8azPW3z12M-Kz1fvP62vy-2Hzc36clvaSilZdih72kHFUPIOOy2aqgHNauw5WAAhbKvrWnHGtOg4UMGkaNuGKc5bbQWvzoq3i-8Uw_djftEMLln0HkYMx2R4zZXSos7guwW0MaQUsTdTdAPEk2HU3GdqcqbmIdPMvnk0hWTB9xFG69I_gVSMyppm7mLhfjqPp_8bmsu7uz_O5aJwacZffxUQD0bpSkvz9XZjbjfb6sv6-qOR1W8tFJaA</recordid><startdate>20040515</startdate><enddate>20040515</enddate><creator>Wang, You</creator><creator>Wang, Binsong</creator><creator>Shen, Jingshu</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20040515</creationdate><title>Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation</title><author>Wang, You ; Wang, Binsong ; Shen, Jingshu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3665-de5f0da31e52ded74939a718ef2acaa44cb788621174d2a04154bb91622b7c423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>block copolymers</topic><topic>Exact sciences and technology</topic><topic>kinetics (polym.)</topic><topic>mechanical properties</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>strain</topic><topic>structure healing</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, You</creatorcontrib><creatorcontrib>Wang, Binsong</creatorcontrib><creatorcontrib>Shen, Jingshu</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, You</au><au>Wang, Binsong</au><au>Shen, Jingshu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2004-05-15</date><risdate>2004</risdate><volume>92</volume><issue>4</issue><spage>2593</spage><epage>2598</epage><pages>2593-2598</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The kinetic mechanism of structure healing after unloading from large elongation for styrene–butadiene–styrene (SBS) block copolymer materials was investigated by following their residual deformation recovery behaviors upon annealing. A linear relationship was found to exist between the deformation recovery percentage and the logarithm of time at different temperatures, which shed light on the mechanism of structure healing. A modified activation energy model was proposed to describe the kinetics of the process. It was also found that the model agrees well with other SBS structure healing–related experimental data such as the recovery of hardness as well as dynamic mechanical property after large elongation. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2593–2598, 2004</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.20235</doi><tpages>6</tpages></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences block copolymers Exact sciences and technology kinetics (polym.) mechanical properties Physicochemistry of polymers Polymer industry, paints, wood strain structure healing Technology of polymers |
| title | Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation |
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