Dual-asymmetrically selective interfaces-enhanced poly(lactic acid)-based nanofabric with sweat management and switchable radiative cooling and thermal insulation

[Display omitted] •Asymmetrically optical surfaces integrate radiative cooling and thermal insulation.•Interfaces-engineered nanofabric achieves ∼12.8℃ cooling and ∼7℃ thermal insulation.•Opposite wettability imparts nanofabric with directional sweat transferring capacity.•Synergistic thermal-wetting regulation can be achieved by simple interface inversion. All-weather personal thermal regulation has far been challenged by variable environments especially the regulatory failure caused by highly-dense solar radiation, low environmental radiation and the fluctuated epidermal moisture in different seasons. Herein, from the design of interface selectivity, dual-asymmetrically optical and wetting selective polylactic acid-based (PLA) Janus-type nanofabric is proposed to achieve on-demand radiative cooling and heating as well as sweat transportation. Hollow TiO2 particles are introduced in PLA nanofabric causing high interface scattering (∼99%) and infrared emission (∼91.2%) as well as surface hydrophobicity (CA > 140°). The strictly optical and wetting selectivity help achieve ∼12.8℃ of net cooling effect under > 1500 W/m2 of solar power and ∼5℃ of cooling advantage higher than cotton fabric and sweat resistance simultaneously. Contrarily, the semi-embedded Ag nanowires (AgNWs) with high conductivity (0.245 Ω/sq) endows the nanofabric with visible water permeability and excellent interface reflection for thermal radiation from body (>65%) thus causing ∼7℃ of thermal shielding. Through simple interface flipping, synergistical cooling-sweat reducing and warming-sweat resisting can be achieved to satisfy the thermal regulation in all weather. Compared with conventional fabrics, multi-functional Janus-type passive personal thermal management nanofabrics would be of great significance to achieve the personal health maintenance and energy sustainability.