D-A-D-T-type four-component radical dual-difunctionalization and acylative azidation of two different alkenes
From a single alkene to two different alkenes! An iron-catalyzed four-component reaction involving an aldehyde, two different alkenes and TMSN 3 is developed to assemble these four reactants in an orderly fashion based on the inherent nucleophilic/electrophilic reaction activity of the radicals and...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (51), p.7986-7989 |
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creator | Liu, Ren-Xiang Chen, Xin Yang, Luo |
description | From a single alkene to two different alkenes! An iron-catalyzed four-component reaction involving an aldehyde, two different alkenes and TMSN
3
is developed to assemble these four reactants in an orderly fashion based on the inherent nucleophilic/electrophilic reaction activity of the radicals and alkenes
via
a double radical addition, providing various multifunctional compounds containing an azido group and two carbonyl groups.
From a single alkene to two different alkenes! An iron-catalyzed four-component reaction of aldehydes, two different alkenes and TMSN
3
is developed to orderly assemble these four reactants according to their inherent nucleo/electrophilic activity. |
doi_str_mv | 10.1039/d3cc01463k |
format | Article |
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3
is developed to assemble these four reactants in an orderly fashion based on the inherent nucleophilic/electrophilic reaction activity of the radicals and alkenes
via
a double radical addition, providing various multifunctional compounds containing an azido group and two carbonyl groups.
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3
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3
is developed to assemble these four reactants in an orderly fashion based on the inherent nucleophilic/electrophilic reaction activity of the radicals and alkenes
via
a double radical addition, providing various multifunctional compounds containing an azido group and two carbonyl groups.
From a single alkene to two different alkenes! An iron-catalyzed four-component reaction of aldehydes, two different alkenes and TMSN
3
is developed to orderly assemble these four reactants according to their inherent nucleo/electrophilic activity.</description><subject>Aldehydes</subject><subject>Alkenes</subject><subject>Carbonyl groups</subject><subject>Carbonyls</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkUtLxDAUhYMovjfulYIbEaJNkzbpcpjxhYKbEdyVmxd0pm3GpFXGX287M45gNvfm5rsHcg5CZyS-ITHNbzVVKiYso_MddEhoxnDKxPvu0Kc55pSlB-gohFncH5KKfXRAeSIYF_wQ1RM8whM8xe1yYSLrOo-VqxeuMU0bedClgirSHVRYl7ZrVFu6BqryG4YmgkZHoJZVf_s0EXyXej13Nmq_XNSvWOMHJajmpjHhBO1ZqII53dRj9HZ_Nx0_4pfXh6fx6AUrSnmLicwSzi3TkuociBXSZhIkI0bEAGkquVG51lZTrgU3Mpci4YoJwrMEEkHoMbpa6y68--hMaIu6DMpUFTTGdaFIREJZLnic9OjlP3TWm9D_cUUJymLBBup6TSnvQvDGFgtf1uCXBYmLIYRiQsfjVQjPPXyxkexkbfQW_XW9B87XgA9q-_qXIv0BVQ2Mzg</recordid><startdate>20230622</startdate><enddate>20230622</enddate><creator>Liu, Ren-Xiang</creator><creator>Chen, Xin</creator><creator>Yang, Luo</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0061-0816</orcidid></search><sort><creationdate>20230622</creationdate><title>D-A-D-T-type four-component radical dual-difunctionalization and acylative azidation of two different alkenes</title><author>Liu, Ren-Xiang ; Chen, Xin ; Yang, Luo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-1b6277f4db3d9a1f8bf6bab41e80aa55b7ec9ddfd37d87eb9b827c481762a2813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aldehydes</topic><topic>Alkenes</topic><topic>Carbonyl groups</topic><topic>Carbonyls</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Ren-Xiang</creatorcontrib><creatorcontrib>Chen, Xin</creatorcontrib><creatorcontrib>Yang, Luo</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Ren-Xiang</au><au>Chen, Xin</au><au>Yang, Luo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>D-A-D-T-type four-component radical dual-difunctionalization and acylative azidation of two different alkenes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2023-06-22</date><risdate>2023</risdate><volume>59</volume><issue>51</issue><spage>7986</spage><epage>7989</epage><pages>7986-7989</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>From a single alkene to two different alkenes! An iron-catalyzed four-component reaction involving an aldehyde, two different alkenes and TMSN
3
is developed to assemble these four reactants in an orderly fashion based on the inherent nucleophilic/electrophilic reaction activity of the radicals and alkenes
via
a double radical addition, providing various multifunctional compounds containing an azido group and two carbonyl groups.
From a single alkene to two different alkenes! An iron-catalyzed four-component reaction of aldehydes, two different alkenes and TMSN
3
is developed to orderly assemble these four reactants according to their inherent nucleo/electrophilic activity.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37284787</pmid><doi>10.1039/d3cc01463k</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-0061-0816</orcidid></addata></record> |
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source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
subjects | Aldehydes Alkenes Carbonyl groups Carbonyls |
title | D-A-D-T-type four-component radical dual-difunctionalization and acylative azidation of two different alkenes |
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