Upgrading the toolbox: Two-photon absorption induced cleavage of Coumarin dimers for light-based 4D printing
The use of light for shaping and changing matter is of high relevance in polymer and material science. Here, a photopolymer method is presented, which comprises the combination of 3D photo-printing at 405 nm light and subsequent modification under two-photon absorption (TPA) conditions at 532 nm lig...
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| Veröffentlicht in: | Macromolecular rapid communications. 2023-09, Vol.44 (17), p.e2300217-e2300217 |
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| container_end_page | e2300217 |
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| container_issue | 17 |
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| container_title | Macromolecular rapid communications. |
| container_volume | 44 |
| creator | Inacker, Sebastian Schipplick, Luca Kahler, Philipp Hampp, Norbert |
| description | The use of light for shaping and changing matter is of high relevance in polymer and material science. Here, a photopolymer method is presented, which comprises the combination of 3D photo-printing at 405 nm light and subsequent modification under two-photon absorption (TPA) conditions at 532 nm light, adding the fourth dimension. The TPA-triggered cycloreversion reaction of an intramolecular coumarin dimer (ICD) structure occurs within the absorbing material. The 3D-printable matrix does not show any degradation under the TPA conditions. With the presented photochemical tool of TPA processes inside absorbing 3D photo-printable matrices, new possibilities for post-printing modification, e. g. for smart materials, are added. This article is protected by copyright. All rights reserved. |
| doi_str_mv | 10.1002/marc.202300217 |
| format | Article |
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| language | eng |
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| source | Access via Wiley Online Library |
| subjects | Absorption Coumarin Dimers Molecular structure Photochemicals Photon absorption Photons Photopolymers Polymers Printing Smart materials Three dimensional printing |
| title | Upgrading the toolbox: Two-photon absorption induced cleavage of Coumarin dimers for light-based 4D printing |
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