Adenophorone, An Unprecedented Sesquiterpene from Eupatorium adenophorum: Structural Elucidation, Bioinspired Total Synthesis and Neuroprotective Activity Evaluation

(−)‐Adenophorone (1), a caged polycyclic sesquiterpene featuring an unprecedented tricyclo[4.3.1.05,9]decane skeleton, was isolated from Eupatorium adenopharum Spreng. The structure of 1 was unambiguously established by a combination of spectroscopic analysis, X‐ray crystallography, and bioinspired...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-08, Vol.62 (31), p.e202306326-n/a
Hauptverfasser:	Yin, Bo, Li, Xiaohuan, Li, Zi‐Xiang, Zhu, Xiao‐Xin, Zhang, Lan, Zhou, Xian‐Li, Xu, Jin‐Bu, Chen, Feng‐Zheng, Tang, Pei, Gao, Feng
Format:	Artikel
Sprache:	eng
Schlagworte:	Adenophorone Cadinene Carvone Crystallography Euptox A Hydrogen peroxide Natural Products Neuroprotection Neuroprotective Activity Oxidation Pheochromocytoma cells Stereoselectivity Synthesis Total Synthesis
Online-Zugang:	Volltext
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