Electrochemical sensing of anions by (ferrocenylmethyl)trialkylammonium cations in homogeneous solution and in polymer films
Based on ion-pairing interactions, which are strongly reinforced upon oxidation to their ferrocenium form, (ferrocenylmethyl)trialkylammonium cations are able to electrochemically sense dihydrogenphosphate and ATP anions in organic electrolytes through two-wave voltammetric features, allowing their...
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| Veröffentlicht in: | Electrochimica acta 2004-09, Vol.49 (22), p.3727-3735 |
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| container_end_page | 3735 |
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| container_issue | 22 |
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| container_title | Electrochimica acta |
| container_volume | 49 |
| creator | Reynes, Olivier Moutet, Jean-Claude Royal, Guy Saint-Aman, Eric |
| description | Based on ion-pairing interactions, which are strongly reinforced upon oxidation to their ferrocenium form, (ferrocenylmethyl)trialkylammonium cations are able to electrochemically sense dihydrogenphosphate and ATP anions in organic electrolytes through two-wave voltammetric features, allowing their amperometric titration. The successful transfer of these electrochemical sensing properties from the homogeneous phase to an electrode surface was achieved using functionalized polypyrrole films synthesized by oxidative polymerization of pyrrole-containing (ferrocenylmethyl)trialkylammonium derivatives. |
| doi_str_mv | 10.1016/j.electacta.2003.12.053 |
| format | Article |
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| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2004-09, Vol.49 (22), p.3727-3735 |
| issn | 0013-4686 1873-3859 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_28226955 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Analytical chemistry ATP Chemistry Dihydrogenphosphate Electrochemical sensing Exact sciences and technology Ferrocene Functionalized polypyrrole General, instrumentation |
| title | Electrochemical sensing of anions by (ferrocenylmethyl)trialkylammonium cations in homogeneous solution and in polymer films |
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