Developments in nanoscience: polyhedral oligomeric silsesquioxane (POSS)-polymers

Developments in nanoscience: polyhedral oligomeric silsesquioxane (POSS)-polymers

This review is intended to cover the more recent advances in both structure–property relationships of polymers incorporating polyhedral oligomeric silsesquioxane(s) (POSS) nanostructured chemicals as well as space-survivability testing of POSS-polymers. The strategy employed for using POSS as buildi...

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Veröffentlicht in:Current opinion in solid state & materials science 2004, Vol.8 (1), p.21-29
Hauptverfasser: Phillips, Shawn H, Haddad, Timothy S, Tomczak, Sandra J
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container_title Current opinion in solid state & materials science
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creator Phillips, Shawn H
Haddad, Timothy S
Tomczak, Sandra J
description This review is intended to cover the more recent advances in both structure–property relationships of polymers incorporating polyhedral oligomeric silsesquioxane(s) (POSS) nanostructured chemicals as well as space-survivability testing of POSS-polymers. The strategy employed for using POSS as building-blocks is discussed in addition to current models and predictions pertaining to the ideal crystallite/aggregate size of the nanocomposite within the polymer matrix to provide maximum mechanical improvements. The oxidation and rapid formation of SiO 2 during atomic oxygen testing leads to a passivating layer, and conclusive proof of these phenomena is presented. Also, a brief history of POSS is outlined to help readers understand how they relate to the recent boom in nanotechnology and their position in nanomaterials R&D.
doi_str_mv 10.1016/j.cossms.2004.03.002
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title Developments in nanoscience: polyhedral oligomeric silsesquioxane (POSS)-polymers
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