Crystalline transition of polyamide-10,20 investigated by in situ Fourier transform infrared spectroscopy
Real‐time Fourier transform infrared spectroscopy was used to investigate the crystalline transition of even–even polyamide‐10,20. During the crystalline transition, the intensity of the hydrogen bonds became weak, the twisting of the CCO and CN bonds improved, and the gauche conformation of the C...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2004-11, Vol.42 (21), p.4017-4022 |
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| container_end_page | 4022 |
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| container_issue | 21 |
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| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 42 |
| creator | Cui, Xiaowen Yan, Deyue |
| description | Real‐time Fourier transform infrared spectroscopy was used to investigate the crystalline transition of even–even polyamide‐10,20. During the crystalline transition, the intensity of the hydrogen bonds became weak, the twisting of the CCO and CN bonds improved, and the gauche conformation of the CH2 sequences increased, along with the strengthening of the vibration of the methylene units. The ordered stacking of methylene segments with the trans‐zigzag conformation gradually became disordered by the insertion of the gauche conformation upon heating. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4017–4022, 2004 |
| doi_str_mv | 10.1002/polb.20266 |
| format | Article |
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J Polym Sci Part B: Polym Phys 42: 4017–4022, 2004</description><subject>Applied sciences</subject><subject>conformation</subject><subject>crystal structures</subject><subject>crystalline transition</subject><subject>Exact sciences and technology</subject><subject>FT-IR</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>polyamides</subject><subject>Properties and characterization</subject><subject>Structure, morphology and analysis</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp9kM1O3DAURq2qlTqlbHiCbNoFIvTajv-WzAiGilFppUEsLcdxKreZONgZIG9f01DYdWXZ93xH1x9CRxhOMQD5MoSuPiVAOH-DFhiUKqGS8i1agJSi5Pn9PfqQ0i-APGNqgfwqTmk0Xed7V4zR9MmPPvRFaIvsmszON67EcEKg8P29S6P_aUbXFPWU70WG98VF2Efv4pxuQ9zlSRtNzFQanB1jSDYM00f0rjVdcofP5wG6uTjfri7LzfX66-psU1oqgJe4tXWtKqEIIbJWzFDKK1crJSQGQgS2jOCqkQIa23CrBFPMMgq8qUWroKEH6PPsHWK42-eN9c4n67rO9C7skyYSV5QAy-DxDNq8YYqu1UP0OxMnjUE_tamf2tR_28zwp2erSdZ0-X-99ek1wbFUtKoyh2fuwXdu-o9Rf7_eLP-5yznj0-geXzIm_tZcUMH07be1vhJbsl0uf2hG_wB8L5Qy</recordid><startdate>20041101</startdate><enddate>20041101</enddate><creator>Cui, Xiaowen</creator><creator>Yan, Deyue</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20041101</creationdate><title>Crystalline transition of polyamide-10,20 investigated by in situ Fourier transform infrared spectroscopy</title><author>Cui, Xiaowen ; Yan, Deyue</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3706-1fcbb94792228b95a3364eb9978102271c5214d870dcd6c97595c5306db7f90d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>conformation</topic><topic>crystal structures</topic><topic>crystalline transition</topic><topic>Exact sciences and technology</topic><topic>FT-IR</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>polyamides</topic><topic>Properties and characterization</topic><topic>Structure, morphology and analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cui, Xiaowen</creatorcontrib><creatorcontrib>Yan, Deyue</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of polymer science. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences conformation crystal structures crystalline transition Exact sciences and technology FT-IR Organic polymers Physicochemistry of polymers polyamides Properties and characterization Structure, morphology and analysis |
| title | Crystalline transition of polyamide-10,20 investigated by in situ Fourier transform infrared spectroscopy |
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