[2+4] Cycloaddition Product of an Amidinate Substituted Dialumene with Toluene
Reduction of LAlI2 (L=PhC(NiPr2C6H3)2) with two equivalents of KC8 in toluene affords the [2+4]cycloaddition product of a dialumene with toluene. The mechanism for the formation of product complex was investigated using density functional theory (DFT) methods. A transient dialumene based on an amidi...
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| Veröffentlicht in: | Chemistry : a European journal 2023-07, Vol.29 (41), p.e202300546-n/a |
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| container_title | Chemistry : a European journal |
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| creator | Kumar, Arun Yadav, Komal Graw, Nico Pandey, Madhusudan K. Herbst‐Irmer, Regine Lourderaj, Upakarasamy Stalke, Dietmar Roesky, Herbert W. |
| description | Reduction of LAlI2 (L=PhC(NiPr2C6H3)2) with two equivalents of KC8 in toluene affords the [2+4]cycloaddition product of a dialumene with toluene. The mechanism for the formation of product complex was investigated using density functional theory (DFT) methods.
A transient dialumene based on an amidinate scaffold was synthesized. The complex was isolated as a cycloaddition product with toluene. The mechanism of the reaction investigated using the DFT method indicates a free energy barrier of 0.9 kcal/mol with respect to the monomeric AlI intermediate. |
| doi_str_mv | 10.1002/chem.202300546 |
| format | Article |
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A transient dialumene based on an amidinate scaffold was synthesized. The complex was isolated as a cycloaddition product with toluene. 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| subjects | aluminum amidinates Chemistry Cycloaddition Density functional theory dialumene Toluene X- ray crystallography |
| title | [2+4] Cycloaddition Product of an Amidinate Substituted Dialumene with Toluene |
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