Atroposelective Sulfenylation of Biaryl Anilines Catalyzed by Chiral SPINOL-Derived Selenide

The atroposelective electrophilic sulfenylation of biaryl anilines has been realized for the first time. The reaction is enabled by a new chiral 6,6′-dianisole substituted SPINOL-derived selenide. A variety of axially chiral sulfur-containing biaryl aniline compounds were obtained in moderate to exc...

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Veröffentlicht in:	Organic letters 2023-05, Vol.25 (19), p.3445-3450
Hauptverfasser:	Zhang, Xin-Yu, Zhu, Deng, Huo, Yu-Xuan, Chen, Ling-Ling, Chen, Zhi-Min
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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