Design of stationary phase properties for optimal performance of reactive simulated-moving-bed chromatography
A relevant role in the performance of a SMBR unit is played by the characteristics of the stationary phase. This is analysed in detail in this work using as a model system the synthesis of methyl acetate on sulphonic resins, for which extensive experimental data on the reaction and equilibrium param...
Gespeichert in:
| Veröffentlicht in: | Chemical engineering science 2004-11, Vol.59 (22), p.4951-4956 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4956 |
|---|---|
| container_issue | 22 |
| container_start_page | 4951 |
| container_title | Chemical engineering science |
| container_volume | 59 |
| creator | Ströhlein, Guido Lode, Florian Mazzotti, Marco Morbidelli, Massimo |
| description | A relevant role in the performance of a SMBR unit is played by the characteristics of the stationary phase. This is analysed in detail in this work using as a model system the synthesis of methyl acetate on sulphonic resins, for which extensive experimental data on the reaction and equilibrium parameters as a function of the acid capacity of the resins are available. It is found that the best suited stationary phase for a SMBR should exhibit large product/product and low product/solvent selectivities and either a large catalytic activity or a large reactant/product selectivity. |
| doi_str_mv | 10.1016/j.ces.2004.07.014 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_28113858</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0009250904004506</els_id><sourcerecordid>28113858</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-c9a98b27c20d7c6e8433aa9b2f8be2ffd26a0c94443a3c89cf3e29068a94e3ce3</originalsourceid><addsrcrecordid>eNp9kE9rGzEQxUVJoU7aD9CbLs1tN_rnXYmcQpo0hUAv7VmMtSNbZne1kWSDv31lHOitp-EN783wfoR85azljHd3-9ZhbgVjqmV9y7j6QFZc97JRiq2vyIoxZhqxZuYTuc55X2Xfc7Yi03fMYTvT6GkuUEKcIZ3osoOMdElxwVQCZupjonEpYYKR1l2VE8wOz7GE4Eo4Is1hOoxQcGimeAzzttngQN0uxQlK3CZYdqfP5KOHMeOX93lD_jw__X58aV5__fj5-PDaOLnuSuMMGL0RvRNs6F2HWkkJYDbC6w0K7wfRAXNGKSVBOm2clygM6zQYhdKhvCG3l7u1wtsBc7FTyA7HEWaMh2yF5lzqta5GfjG6FHNO6O2Sasl0spzZM1i7txWsPYO1rLcVbM18ez8O2cHoUyUR8r9gJytZ1VXf_cWHtekxYLLZBazUhpDQFTvE8J8vfwHOKJDO</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>28113858</pqid></control><display><type>article</type><title>Design of stationary phase properties for optimal performance of reactive simulated-moving-bed chromatography</title><source>Elsevier ScienceDirect Journals</source><creator>Ströhlein, Guido ; Lode, Florian ; Mazzotti, Marco ; Morbidelli, Massimo</creator><creatorcontrib>Ströhlein, Guido ; Lode, Florian ; Mazzotti, Marco ; Morbidelli, Massimo</creatorcontrib><description>A relevant role in the performance of a SMBR unit is played by the characteristics of the stationary phase. This is analysed in detail in this work using as a model system the synthesis of methyl acetate on sulphonic resins, for which extensive experimental data on the reaction and equilibrium parameters as a function of the acid capacity of the resins are available. It is found that the best suited stationary phase for a SMBR should exhibit large product/product and low product/solvent selectivities and either a large catalytic activity or a large reactant/product selectivity.</description><identifier>ISSN: 0009-2509</identifier><identifier>EISSN: 1873-4405</identifier><identifier>DOI: 10.1016/j.ces.2004.07.014</identifier><identifier>CODEN: CESCAC</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Catalysis ; Catalytic reactions ; Chemical engineering ; Chemical reactors ; Chemistry ; Chromatography ; Exact sciences and technology ; General and physical chemistry ; Optimisation ; Reactors ; Simulated-moving-bed ; Simulation ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Chemical engineering science, 2004-11, Vol.59 (22), p.4951-4956</ispartof><rights>2004 Elsevier Ltd</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-c9a98b27c20d7c6e8433aa9b2f8be2ffd26a0c94443a3c89cf3e29068a94e3ce3</citedby><cites>FETCH-LOGICAL-c356t-c9a98b27c20d7c6e8433aa9b2f8be2ffd26a0c94443a3c89cf3e29068a94e3ce3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0009250904004506$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,3537,23909,23910,25118,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16371046$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ströhlein, Guido</creatorcontrib><creatorcontrib>Lode, Florian</creatorcontrib><creatorcontrib>Mazzotti, Marco</creatorcontrib><creatorcontrib>Morbidelli, Massimo</creatorcontrib><title>Design of stationary phase properties for optimal performance of reactive simulated-moving-bed chromatography</title><title>Chemical engineering science</title><description>A relevant role in the performance of a SMBR unit is played by the characteristics of the stationary phase. This is analysed in detail in this work using as a model system the synthesis of methyl acetate on sulphonic resins, for which extensive experimental data on the reaction and equilibrium parameters as a function of the acid capacity of the resins are available. It is found that the best suited stationary phase for a SMBR should exhibit large product/product and low product/solvent selectivities and either a large catalytic activity or a large reactant/product selectivity.</description><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalytic reactions</subject><subject>Chemical engineering</subject><subject>Chemical reactors</subject><subject>Chemistry</subject><subject>Chromatography</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Optimisation</subject><subject>Reactors</subject><subject>Simulated-moving-bed</subject><subject>Simulation</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>0009-2509</issn><issn>1873-4405</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp9kE9rGzEQxUVJoU7aD9CbLs1tN_rnXYmcQpo0hUAv7VmMtSNbZne1kWSDv31lHOitp-EN783wfoR85azljHd3-9ZhbgVjqmV9y7j6QFZc97JRiq2vyIoxZhqxZuYTuc55X2Xfc7Yi03fMYTvT6GkuUEKcIZ3osoOMdElxwVQCZupjonEpYYKR1l2VE8wOz7GE4Eo4Is1hOoxQcGimeAzzttngQN0uxQlK3CZYdqfP5KOHMeOX93lD_jw__X58aV5__fj5-PDaOLnuSuMMGL0RvRNs6F2HWkkJYDbC6w0K7wfRAXNGKSVBOm2clygM6zQYhdKhvCG3l7u1wtsBc7FTyA7HEWaMh2yF5lzqta5GfjG6FHNO6O2Sasl0spzZM1i7txWsPYO1rLcVbM18ez8O2cHoUyUR8r9gJytZ1VXf_cWHtekxYLLZBazUhpDQFTvE8J8vfwHOKJDO</recordid><startdate>20041101</startdate><enddate>20041101</enddate><creator>Ströhlein, Guido</creator><creator>Lode, Florian</creator><creator>Mazzotti, Marco</creator><creator>Morbidelli, Massimo</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20041101</creationdate><title>Design of stationary phase properties for optimal performance of reactive simulated-moving-bed chromatography</title><author>Ströhlein, Guido ; Lode, Florian ; Mazzotti, Marco ; Morbidelli, Massimo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-c9a98b27c20d7c6e8433aa9b2f8be2ffd26a0c94443a3c89cf3e29068a94e3ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Catalysis</topic><topic>Catalytic reactions</topic><topic>Chemical engineering</topic><topic>Chemical reactors</topic><topic>Chemistry</topic><topic>Chromatography</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Optimisation</topic><topic>Reactors</topic><topic>Simulated-moving-bed</topic><topic>Simulation</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ströhlein, Guido</creatorcontrib><creatorcontrib>Lode, Florian</creatorcontrib><creatorcontrib>Mazzotti, Marco</creatorcontrib><creatorcontrib>Morbidelli, Massimo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Chemical engineering science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ströhlein, Guido</au><au>Lode, Florian</au><au>Mazzotti, Marco</au><au>Morbidelli, Massimo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design of stationary phase properties for optimal performance of reactive simulated-moving-bed chromatography</atitle><jtitle>Chemical engineering science</jtitle><date>2004-11-01</date><risdate>2004</risdate><volume>59</volume><issue>22</issue><spage>4951</spage><epage>4956</epage><pages>4951-4956</pages><issn>0009-2509</issn><eissn>1873-4405</eissn><coden>CESCAC</coden><abstract>A relevant role in the performance of a SMBR unit is played by the characteristics of the stationary phase. This is analysed in detail in this work using as a model system the synthesis of methyl acetate on sulphonic resins, for which extensive experimental data on the reaction and equilibrium parameters as a function of the acid capacity of the resins are available. It is found that the best suited stationary phase for a SMBR should exhibit large product/product and low product/solvent selectivities and either a large catalytic activity or a large reactant/product selectivity.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.ces.2004.07.014</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0009-2509 |
| ispartof | Chemical engineering science, 2004-11, Vol.59 (22), p.4951-4956 |
| issn | 0009-2509 1873-4405 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_28113858 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Catalysis Catalytic reactions Chemical engineering Chemical reactors Chemistry Chromatography Exact sciences and technology General and physical chemistry Optimisation Reactors Simulated-moving-bed Simulation Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Design of stationary phase properties for optimal performance of reactive simulated-moving-bed chromatography |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-21T16%3A00%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Design%20of%20stationary%20phase%20properties%20for%20optimal%20performance%20of%20reactive%20simulated-moving-bed%20chromatography&rft.jtitle=Chemical%20engineering%20science&rft.au=Str%C3%B6hlein,%20Guido&rft.date=2004-11-01&rft.volume=59&rft.issue=22&rft.spage=4951&rft.epage=4956&rft.pages=4951-4956&rft.issn=0009-2509&rft.eissn=1873-4405&rft.coden=CESCAC&rft_id=info:doi/10.1016/j.ces.2004.07.014&rft_dat=%3Cproquest_cross%3E28113858%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=28113858&rft_id=info:pmid/&rft_els_id=S0009250904004506&rfr_iscdi=true |