Shift‐Current Photovoltaics Based on a Non‐Centrosymmetric Phase in In‐Plane Ferroelectric SnS

The shift‐current photovoltaics of group‐IV monochalcogenides has been predicted to be comparable to those of state‐of‐the‐art Si‐based solar cells. However, its exploration has been prevented from the centrosymmetric layer stacking in the thermodynamically stable bulk crystal. Herein, the non‐centr...

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Veröffentlicht in:Advanced materials (Weinheim) 2023-07, Vol.35 (29), p.e2301172-n/a
Hauptverfasser: Chang, Yih‐Ren, Nanae, Ryo, Kitamura, Satsuki, Nishimura, Tomonori, Wang, Haonan, Xiang, Yubei, Shinokita, Keisuke, Matsuda, Kazunari, Taniguchi, Takashi, Watanabe, Kenji, Nagashio, Kosuke
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container_issue 29
container_start_page e2301172
container_title Advanced materials (Weinheim)
container_volume 35
creator Chang, Yih‐Ren
Nanae, Ryo
Kitamura, Satsuki
Nishimura, Tomonori
Wang, Haonan
Xiang, Yubei
Shinokita, Keisuke
Matsuda, Kazunari
Taniguchi, Takashi
Watanabe, Kenji
Nagashio, Kosuke
description The shift‐current photovoltaics of group‐IV monochalcogenides has been predicted to be comparable to those of state‐of‐the‐art Si‐based solar cells. However, its exploration has been prevented from the centrosymmetric layer stacking in the thermodynamically stable bulk crystal. Herein, the non‐centrosymmetric layer stacking of tin sulfide (SnS) is stabilized in the bottom regions of SnS crystals grown on a van der Waals substrate by physical vapor deposition and the shift current of SnS, by combining the polarization angle dependence and circular photogalvanic effect, is demonstrated. Furthermore, 180° ferroelectric domains in SnS are verified through both piezoresponse force microscopy and shift‐current mapping techniques. Based on these results, an atomic model of the ferroelectric domain boundary is proposed. The direct observation of shift current and ferroelectric domains reported herein paves a new path for future studies on shift‐current photovoltaics. A non‐centrosymmetric layer stacking phase of 2D tin sulfide (SnS) is successfully achieved on van der Waals substrates and the shift current in SnS is demonstrated. Following the PFM observation that reveals the existence of ferroelectric domains, an atomic model of the ferroelectric domain boundary is proposed.
doi_str_mv 10.1002/adma.202301172
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subjects 2D materials
Crystal growth
Ferroelectric domains
Ferroelectric materials
Ferroelectricity
non‐centrosymmetry
Photovoltaic cells
Physical vapor deposition
shift currents
Solar cells
Stacking
Substrates
tin sulfide
title Shift‐Current Photovoltaics Based on a Non‐Centrosymmetric Phase in In‐Plane Ferroelectric SnS
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