Catalytic Enantioselective Amination of Enol Silyl Ethers Using a Chiral Paddle-Wheel Diruthenium Complex

A chiral paddle-wheel dinuclear ruthenium catalyst was applied to a catalytic asymmetric nitrene-transfer reaction with enol silyl ethers. The ruthenium catalyst was applicable to aliphatic enol silyl ethers as well as aryl-containing enol silyl ethers. The substrate scope of the ruthenium catalyst...

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Veröffentlicht in:	Organic letters 2023-05, Vol.25 (18), p.3234-3238
Hauptverfasser:	Makino, Kotoko, Kumagai, Yuhei, Yoshino, Tatsuhiko, Kojima, Masahiro, Matsunaga, Shigeki
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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