Unraveling the Reaction Mystery of Li and Na with Dry Air
Li and Na metals with high energy density are promising in application in rechargeable batteries but suffer from degradation in the ambient atmosphere. The phenomenon that in terms of kinetics, Li is stable but Na is unstable in dry air has not been fully understood. Here, we use in situ environment...
Gespeichert in:
| Veröffentlicht in: | Journal of the American Chemical Society 2023-05, Vol.145 (19), p.10576-10583 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 10583 |
|---|---|
| container_issue | 19 |
| container_start_page | 10576 |
| container_title | Journal of the American Chemical Society |
| container_volume | 145 |
| creator | Li, Yuqi Liu, Qiunan Wu, Siyuan Geng, Lin Popovic, Jelena Li, Yu Chen, Zhao Wang, Haibo Wang, Yuqi Dai, Tao Yang, Yang Sun, Haiming Lu, Yaxiang Zhang, Liqiang Tang, Yongfu Xiao, Ruijuan Li, Hong Chen, Liquan Maier, Joachim Huang, Jianyu Hu, Yong-Sheng |
| description | Li and Na metals with high energy density are promising in application in rechargeable batteries but suffer from degradation in the ambient atmosphere. The phenomenon that in terms of kinetics, Li is stable but Na is unstable in dry air has not been fully understood. Here, we use in situ environmental transmission electron microscopy combined with theoretical simulations and reveal that the different stabilities in dry air for Li and Na are reflected by the formation of compact Li2O layers on Li metal, while porous and rough Na2O/Na2O2 layers on Na metal are a consequence of the different thermodynamic and kinetics in O2. It is shown that a preformed carbonate layer can change the kinetics of Na toward an anticorrosive behavior. Our study provides a deeper understanding of the often-overlooked chemical reactions with environmental gases and enhances the electrochemical performance of Li and Na by controlling interfacial stability. |
| doi_str_mv | 10.1021/jacs.2c13589 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2809004318</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2809004318</sourcerecordid><originalsourceid>FETCH-LOGICAL-a357t-6b7552af023b980b3f31f0ef89764bfa740e6e3d04ddbfd69bb0e3365ce447213</originalsourceid><addsrcrecordid>eNqFkE1Lw0AQhhdRbP24eZY9ejB19iObzbHUT6gKYs9hN5m1KWlSdxOl_96UVr0InoYZnvcdeAg5YzBiwNnVwuRhxHMmYp3ukSGLOUQx42qfDAGAR4lWYkCOQlj0q-SaHZKBSJgArmBI0lntzQdWZf1G2znSFzR5WzY1fVyHFv2aNo5OS2rqgj4Z-lm2c3rdX8elPyEHzlQBT3fzmMxub14n99H0-e5hMp5GRsRJGymbxDE3DriwqQYrnGAO0Ok0UdI6k0hAhaIAWRTWFSq1FlAIFecoZcKZOCYX296Vb947DG22LEOOVWVqbLqQCZAgFddS_ItyDWnvQDDdo5dbNPdNCB5dtvLl0vh1xiDbeM02XrOd1x4_3zV3donFD_wt8vf1JrVoOl_3Tv7u-gK6434t</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2809004318</pqid></control><display><type>article</type><title>Unraveling the Reaction Mystery of Li and Na with Dry Air</title><source>ACS Publications</source><creator>Li, Yuqi ; Liu, Qiunan ; Wu, Siyuan ; Geng, Lin ; Popovic, Jelena ; Li, Yu ; Chen, Zhao ; Wang, Haibo ; Wang, Yuqi ; Dai, Tao ; Yang, Yang ; Sun, Haiming ; Lu, Yaxiang ; Zhang, Liqiang ; Tang, Yongfu ; Xiao, Ruijuan ; Li, Hong ; Chen, Liquan ; Maier, Joachim ; Huang, Jianyu ; Hu, Yong-Sheng</creator><creatorcontrib>Li, Yuqi ; Liu, Qiunan ; Wu, Siyuan ; Geng, Lin ; Popovic, Jelena ; Li, Yu ; Chen, Zhao ; Wang, Haibo ; Wang, Yuqi ; Dai, Tao ; Yang, Yang ; Sun, Haiming ; Lu, Yaxiang ; Zhang, Liqiang ; Tang, Yongfu ; Xiao, Ruijuan ; Li, Hong ; Chen, Liquan ; Maier, Joachim ; Huang, Jianyu ; Hu, Yong-Sheng</creatorcontrib><description>Li and Na metals with high energy density are promising in application in rechargeable batteries but suffer from degradation in the ambient atmosphere. The phenomenon that in terms of kinetics, Li is stable but Na is unstable in dry air has not been fully understood. Here, we use in situ environmental transmission electron microscopy combined with theoretical simulations and reveal that the different stabilities in dry air for Li and Na are reflected by the formation of compact Li2O layers on Li metal, while porous and rough Na2O/Na2O2 layers on Na metal are a consequence of the different thermodynamic and kinetics in O2. It is shown that a preformed carbonate layer can change the kinetics of Na toward an anticorrosive behavior. Our study provides a deeper understanding of the often-overlooked chemical reactions with environmental gases and enhances the electrochemical performance of Li and Na by controlling interfacial stability.</description><identifier>ISSN: 0002-7863</identifier><identifier>ISSN: 1520-5126</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/jacs.2c13589</identifier><identifier>PMID: 37130260</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>air ; carbonates ; electrochemistry ; energy density ; thermodynamics ; transmission electron microscopy</subject><ispartof>Journal of the American Chemical Society, 2023-05, Vol.145 (19), p.10576-10583</ispartof><rights>2023 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a357t-6b7552af023b980b3f31f0ef89764bfa740e6e3d04ddbfd69bb0e3365ce447213</citedby><cites>FETCH-LOGICAL-a357t-6b7552af023b980b3f31f0ef89764bfa740e6e3d04ddbfd69bb0e3365ce447213</cites><orcidid>0000-0003-3684-5841 ; 0000-0002-8424-5368 ; 0000-0002-8430-6474 ; 0000-0003-0930-9576 ; 0000-0002-8659-086X ; 0000-0002-6318-3110 ; 0000-0001-9085-500X ; 0000-0003-2274-6068 ; 0000-0002-3111-3724 ; 0000-0001-5202-175X ; 0000-0003-1501-1549</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jacs.2c13589$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jacs.2c13589$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37130260$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Yuqi</creatorcontrib><creatorcontrib>Liu, Qiunan</creatorcontrib><creatorcontrib>Wu, Siyuan</creatorcontrib><creatorcontrib>Geng, Lin</creatorcontrib><creatorcontrib>Popovic, Jelena</creatorcontrib><creatorcontrib>Li, Yu</creatorcontrib><creatorcontrib>Chen, Zhao</creatorcontrib><creatorcontrib>Wang, Haibo</creatorcontrib><creatorcontrib>Wang, Yuqi</creatorcontrib><creatorcontrib>Dai, Tao</creatorcontrib><creatorcontrib>Yang, Yang</creatorcontrib><creatorcontrib>Sun, Haiming</creatorcontrib><creatorcontrib>Lu, Yaxiang</creatorcontrib><creatorcontrib>Zhang, Liqiang</creatorcontrib><creatorcontrib>Tang, Yongfu</creatorcontrib><creatorcontrib>Xiao, Ruijuan</creatorcontrib><creatorcontrib>Li, Hong</creatorcontrib><creatorcontrib>Chen, Liquan</creatorcontrib><creatorcontrib>Maier, Joachim</creatorcontrib><creatorcontrib>Huang, Jianyu</creatorcontrib><creatorcontrib>Hu, Yong-Sheng</creatorcontrib><title>Unraveling the Reaction Mystery of Li and Na with Dry Air</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Li and Na metals with high energy density are promising in application in rechargeable batteries but suffer from degradation in the ambient atmosphere. The phenomenon that in terms of kinetics, Li is stable but Na is unstable in dry air has not been fully understood. Here, we use in situ environmental transmission electron microscopy combined with theoretical simulations and reveal that the different stabilities in dry air for Li and Na are reflected by the formation of compact Li2O layers on Li metal, while porous and rough Na2O/Na2O2 layers on Na metal are a consequence of the different thermodynamic and kinetics in O2. It is shown that a preformed carbonate layer can change the kinetics of Na toward an anticorrosive behavior. Our study provides a deeper understanding of the often-overlooked chemical reactions with environmental gases and enhances the electrochemical performance of Li and Na by controlling interfacial stability.</description><subject>air</subject><subject>carbonates</subject><subject>electrochemistry</subject><subject>energy density</subject><subject>thermodynamics</subject><subject>transmission electron microscopy</subject><issn>0002-7863</issn><issn>1520-5126</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkE1Lw0AQhhdRbP24eZY9ejB19iObzbHUT6gKYs9hN5m1KWlSdxOl_96UVr0InoYZnvcdeAg5YzBiwNnVwuRhxHMmYp3ukSGLOUQx42qfDAGAR4lWYkCOQlj0q-SaHZKBSJgArmBI0lntzQdWZf1G2znSFzR5WzY1fVyHFv2aNo5OS2rqgj4Z-lm2c3rdX8elPyEHzlQBT3fzmMxub14n99H0-e5hMp5GRsRJGymbxDE3DriwqQYrnGAO0Ok0UdI6k0hAhaIAWRTWFSq1FlAIFecoZcKZOCYX296Vb947DG22LEOOVWVqbLqQCZAgFddS_ItyDWnvQDDdo5dbNPdNCB5dtvLl0vh1xiDbeM02XrOd1x4_3zV3donFD_wt8vf1JrVoOl_3Tv7u-gK6434t</recordid><startdate>20230517</startdate><enddate>20230517</enddate><creator>Li, Yuqi</creator><creator>Liu, Qiunan</creator><creator>Wu, Siyuan</creator><creator>Geng, Lin</creator><creator>Popovic, Jelena</creator><creator>Li, Yu</creator><creator>Chen, Zhao</creator><creator>Wang, Haibo</creator><creator>Wang, Yuqi</creator><creator>Dai, Tao</creator><creator>Yang, Yang</creator><creator>Sun, Haiming</creator><creator>Lu, Yaxiang</creator><creator>Zhang, Liqiang</creator><creator>Tang, Yongfu</creator><creator>Xiao, Ruijuan</creator><creator>Li, Hong</creator><creator>Chen, Liquan</creator><creator>Maier, Joachim</creator><creator>Huang, Jianyu</creator><creator>Hu, Yong-Sheng</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0003-3684-5841</orcidid><orcidid>https://orcid.org/0000-0002-8424-5368</orcidid><orcidid>https://orcid.org/0000-0002-8430-6474</orcidid><orcidid>https://orcid.org/0000-0003-0930-9576</orcidid><orcidid>https://orcid.org/0000-0002-8659-086X</orcidid><orcidid>https://orcid.org/0000-0002-6318-3110</orcidid><orcidid>https://orcid.org/0000-0001-9085-500X</orcidid><orcidid>https://orcid.org/0000-0003-2274-6068</orcidid><orcidid>https://orcid.org/0000-0002-3111-3724</orcidid><orcidid>https://orcid.org/0000-0001-5202-175X</orcidid><orcidid>https://orcid.org/0000-0003-1501-1549</orcidid></search><sort><creationdate>20230517</creationdate><title>Unraveling the Reaction Mystery of Li and Na with Dry Air</title><author>Li, Yuqi ; Liu, Qiunan ; Wu, Siyuan ; Geng, Lin ; Popovic, Jelena ; Li, Yu ; Chen, Zhao ; Wang, Haibo ; Wang, Yuqi ; Dai, Tao ; Yang, Yang ; Sun, Haiming ; Lu, Yaxiang ; Zhang, Liqiang ; Tang, Yongfu ; Xiao, Ruijuan ; Li, Hong ; Chen, Liquan ; Maier, Joachim ; Huang, Jianyu ; Hu, Yong-Sheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a357t-6b7552af023b980b3f31f0ef89764bfa740e6e3d04ddbfd69bb0e3365ce447213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>air</topic><topic>carbonates</topic><topic>electrochemistry</topic><topic>energy density</topic><topic>thermodynamics</topic><topic>transmission electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Yuqi</creatorcontrib><creatorcontrib>Liu, Qiunan</creatorcontrib><creatorcontrib>Wu, Siyuan</creatorcontrib><creatorcontrib>Geng, Lin</creatorcontrib><creatorcontrib>Popovic, Jelena</creatorcontrib><creatorcontrib>Li, Yu</creatorcontrib><creatorcontrib>Chen, Zhao</creatorcontrib><creatorcontrib>Wang, Haibo</creatorcontrib><creatorcontrib>Wang, Yuqi</creatorcontrib><creatorcontrib>Dai, Tao</creatorcontrib><creatorcontrib>Yang, Yang</creatorcontrib><creatorcontrib>Sun, Haiming</creatorcontrib><creatorcontrib>Lu, Yaxiang</creatorcontrib><creatorcontrib>Zhang, Liqiang</creatorcontrib><creatorcontrib>Tang, Yongfu</creatorcontrib><creatorcontrib>Xiao, Ruijuan</creatorcontrib><creatorcontrib>Li, Hong</creatorcontrib><creatorcontrib>Chen, Liquan</creatorcontrib><creatorcontrib>Maier, Joachim</creatorcontrib><creatorcontrib>Huang, Jianyu</creatorcontrib><creatorcontrib>Hu, Yong-Sheng</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Yuqi</au><au>Liu, Qiunan</au><au>Wu, Siyuan</au><au>Geng, Lin</au><au>Popovic, Jelena</au><au>Li, Yu</au><au>Chen, Zhao</au><au>Wang, Haibo</au><au>Wang, Yuqi</au><au>Dai, Tao</au><au>Yang, Yang</au><au>Sun, Haiming</au><au>Lu, Yaxiang</au><au>Zhang, Liqiang</au><au>Tang, Yongfu</au><au>Xiao, Ruijuan</au><au>Li, Hong</au><au>Chen, Liquan</au><au>Maier, Joachim</au><au>Huang, Jianyu</au><au>Hu, Yong-Sheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unraveling the Reaction Mystery of Li and Na with Dry Air</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2023-05-17</date><risdate>2023</risdate><volume>145</volume><issue>19</issue><spage>10576</spage><epage>10583</epage><pages>10576-10583</pages><issn>0002-7863</issn><issn>1520-5126</issn><eissn>1520-5126</eissn><abstract>Li and Na metals with high energy density are promising in application in rechargeable batteries but suffer from degradation in the ambient atmosphere. The phenomenon that in terms of kinetics, Li is stable but Na is unstable in dry air has not been fully understood. Here, we use in situ environmental transmission electron microscopy combined with theoretical simulations and reveal that the different stabilities in dry air for Li and Na are reflected by the formation of compact Li2O layers on Li metal, while porous and rough Na2O/Na2O2 layers on Na metal are a consequence of the different thermodynamic and kinetics in O2. It is shown that a preformed carbonate layer can change the kinetics of Na toward an anticorrosive behavior. Our study provides a deeper understanding of the often-overlooked chemical reactions with environmental gases and enhances the electrochemical performance of Li and Na by controlling interfacial stability.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>37130260</pmid><doi>10.1021/jacs.2c13589</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-3684-5841</orcidid><orcidid>https://orcid.org/0000-0002-8424-5368</orcidid><orcidid>https://orcid.org/0000-0002-8430-6474</orcidid><orcidid>https://orcid.org/0000-0003-0930-9576</orcidid><orcidid>https://orcid.org/0000-0002-8659-086X</orcidid><orcidid>https://orcid.org/0000-0002-6318-3110</orcidid><orcidid>https://orcid.org/0000-0001-9085-500X</orcidid><orcidid>https://orcid.org/0000-0003-2274-6068</orcidid><orcidid>https://orcid.org/0000-0002-3111-3724</orcidid><orcidid>https://orcid.org/0000-0001-5202-175X</orcidid><orcidid>https://orcid.org/0000-0003-1501-1549</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2023-05, Vol.145 (19), p.10576-10583 |
| issn | 0002-7863 1520-5126 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2809004318 |
| source | ACS Publications |
| subjects | air carbonates electrochemistry energy density thermodynamics transmission electron microscopy |
| title | Unraveling the Reaction Mystery of Li and Na with Dry Air |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T18%3A21%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Unraveling%20the%20Reaction%20Mystery%20of%20Li%20and%20Na%20with%20Dry%20Air&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Li,%20Yuqi&rft.date=2023-05-17&rft.volume=145&rft.issue=19&rft.spage=10576&rft.epage=10583&rft.pages=10576-10583&rft.issn=0002-7863&rft.eissn=1520-5126&rft_id=info:doi/10.1021/jacs.2c13589&rft_dat=%3Cproquest_cross%3E2809004318%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2809004318&rft_id=info:pmid/37130260&rfr_iscdi=true |