Cationic dialdehyde cellulose microfibers for efficient removal of eriochrome black T from aqueous solution

[Display omitted] •An agroindustrial residue transformed into a new type of biosorbent.•From sugarcane bagasse to cationic dialdehyde cellulose (cDAC) by a simple method.•Efficient removal of emerging contaminant from water.•The interaction mechanism is explained by the non-linear Langmuir isotherm...

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Veröffentlicht in:Bioresource technology 2023-07, Vol.380, p.129096-129096, Article 129096
Hauptverfasser: Silva Gomes, Andressa, Vitória Guimarães Leal, Maria, Roefero Tolosa, Gabrieli, Camargo Cabrera, Flávio, Dognani, Guilherme, Eloízo Job, Aldo
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container_end_page 129096
container_issue
container_start_page 129096
container_title Bioresource technology
container_volume 380
creator Silva Gomes, Andressa
Vitória Guimarães Leal, Maria
Roefero Tolosa, Gabrieli
Camargo Cabrera, Flávio
Dognani, Guilherme
Eloízo Job, Aldo
description [Display omitted] •An agroindustrial residue transformed into a new type of biosorbent.•From sugarcane bagasse to cationic dialdehyde cellulose (cDAC) by a simple method.•Efficient removal of emerging contaminant from water.•The interaction mechanism is explained by the non-linear Langmuir isotherm model.•Recyclable biosorbent, which can be applied efficiently 4 times. Materials based on cellulose have been widely used as a decontaminant agent of wastewater. However, it can not be found in the literature any application of the cationic dialdehyde cellulose (cDAC) in anionic dye removal. Therefore, this study aims a circular economy concept using sugarcane bagasse to obtain a functionalized cellulose by oxidation and cationization. cDAC was characterized by SEM, FT-IR, oxidation degree, and DSC. Adsorption capacity was evaluated by pH, kinetic, concentration effect, strength ionic tests, and recycling. The kinetic followed Elovich model (R2 = 0.92605 for EBT = 100 mg/L) and non-linear Langmuir model (R2 = 0.94542), which resulted in a maximum adsorption capacity of 563.30 mg/g. The cellulose adsorbent reached an efficient recyclability of 4 cycles. Thus, this work presents a potential material to become a new, clean, low-cost, recyclable, and environmentally friendly alternative for effluent decontamination-containing dyes.
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Materials based on cellulose have been widely used as a decontaminant agent of wastewater. However, it can not be found in the literature any application of the cationic dialdehyde cellulose (cDAC) in anionic dye removal. Therefore, this study aims a circular economy concept using sugarcane bagasse to obtain a functionalized cellulose by oxidation and cationization. cDAC was characterized by SEM, FT-IR, oxidation degree, and DSC. Adsorption capacity was evaluated by pH, kinetic, concentration effect, strength ionic tests, and recycling. The kinetic followed Elovich model (R2 = 0.92605 for EBT = 100 mg/L) and non-linear Langmuir model (R2 = 0.94542), which resulted in a maximum adsorption capacity of 563.30 mg/g. The cellulose adsorbent reached an efficient recyclability of 4 cycles. 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Materials based on cellulose have been widely used as a decontaminant agent of wastewater. However, it can not be found in the literature any application of the cationic dialdehyde cellulose (cDAC) in anionic dye removal. Therefore, this study aims a circular economy concept using sugarcane bagasse to obtain a functionalized cellulose by oxidation and cationization. cDAC was characterized by SEM, FT-IR, oxidation degree, and DSC. Adsorption capacity was evaluated by pH, kinetic, concentration effect, strength ionic tests, and recycling. The kinetic followed Elovich model (R2 = 0.92605 for EBT = 100 mg/L) and non-linear Langmuir model (R2 = 0.94542), which resulted in a maximum adsorption capacity of 563.30 mg/g. The cellulose adsorbent reached an efficient recyclability of 4 cycles. 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subjects Adsorption
Biosorbents
Cationic Dialdehyde Cellulose
Cations - chemistry
Cellulose - chemistry
Coloring Agents - chemistry
Eriochrome Black T
Kinetics
Microfibers
Saccharum - chemistry
Spectroscopy, Fourier Transform Infrared
Water Pollutants, Chemical - chemistry
title Cationic dialdehyde cellulose microfibers for efficient removal of eriochrome black T from aqueous solution
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