Thermodynamic reevaluation of the Cu-Zn system by electromotive force measurements in the zinc-rich part

Thermodynamic reevaluation of the Cu-Zn system by electromotive force measurements in the zinc-rich part

In this work, the Cu-Zn system was explored for alloys in the zinc-rich part above 90 at.% zinc between 643 and 843 K by electromotive force measurements. Modeling was then done and was based on the generally well-accepted description of the binary system as in the last assessment proposed by Kowals...

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Veröffentlicht in:Journal of Phase Equilibria 2003-06, Vol.24 (3), p.240-248
Hauptverfasser: David, N., Fiorani, J-M., Vilasi, M., Hertz, J.
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creator David, N.
Fiorani, J-M.
Vilasi, M.
Hertz, J.
description In this work, the Cu-Zn system was explored for alloys in the zinc-rich part above 90 at.% zinc between 643 and 843 K by electromotive force measurements. Modeling was then done and was based on the generally well-accepted description of the binary system as in the last assessment proposed by Kowalski and Spencer [1993Kow] taking into account recent thermodynamic data available in literature. The resulting optimized coefficients are in good agreement with experimental observations.
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