Divergent Synthesis of Alcohols and Ketones via Cross‐Coupling of Secondary Alcohols under Manganese Catalysis

A homogeneous manganese‐catalyzed cross‐coupling of two secondary alcohols for the divergent synthesis of γ‐disubstituted alcohols and β‐disubstituted ketones is reported. Employing the well‐defined Mn‐MACHOPh as the catalyst, this novel protocol has a broad substrate scope with good functional grou...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-06, Vol.62 (26), p.e202303433-n/a
Hauptverfasser:	Sun, Feixiang, Huang, Jiamin, Wei, Zhihong, Tang, Conghui, Liu, Weiping
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Borrowing Hydrogen Catalysis Catalysts Cross coupling Divergence Free energy Functional groups Gibbs free energy Homogeneous Catalysis Ketones Low temperature Manganese Molecular Structure Oxidation-Reduction Substrates Synthesis
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