The influence of steel surface modification by electrodeposited Zn–Fe alloys on the protective behaviour of an epoxy coating

The electrochemical and transport properties of epoxy coatings electrodeposited on steel and steel modified by Zn–Fe alloys were investigated during exposure to 3% NaCl. The Zn–Fe alloys were deposited on steel surface from alkaline bath galvanostatically using different current densities. From the...

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Veröffentlicht in:Progress in organic coatings 2003-07, Vol.47 (1), p.49-54
Hauptverfasser: Bajat, J.B, Mišković-Stanković, V.B, Kačarević-Popović, Z
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container_issue 1
container_start_page 49
container_title Progress in organic coatings
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creator Bajat, J.B
Mišković-Stanković, V.B
Kačarević-Popović, Z
description The electrochemical and transport properties of epoxy coatings electrodeposited on steel and steel modified by Zn–Fe alloys were investigated during exposure to 3% NaCl. The Zn–Fe alloys were deposited on steel surface from alkaline bath galvanostatically using different current densities. From the time dependence of pore resistance of epoxy coating (impedance measurements), diffusion coefficient of water through epoxy coating (gravimetric liquid sorption measurements) and water content in the epoxy coating (thermogravimetric analysis), it was shown that Zn–Fe sublayer could improve the corrosion stability of the protective system based on epoxy coating. The values of the pore resistance were almost unchanged over the long period of immersion time for epoxy coating on steel modified by Zn–Fe alloy deposited by 4 A dm −2, indicating the great stability of this protective system. The values of diffusion coefficient of water through epoxy coating on this alloy and water content inside the epoxy coating were the smallest, indicating the low porosity of the coating.
doi_str_mv 10.1016/S0300-9440(03)00020-1
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subjects Applied sciences
Coatings. Paints, varnishes and inks
Corrosion
EIS
Electrodeposition
Epoxy coatings
Exact sciences and technology
Film formation and curing, properties, testing
Polymer industry, paints, wood
Steel
Zn–Fe alloys
title The influence of steel surface modification by electrodeposited Zn–Fe alloys on the protective behaviour of an epoxy coating
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