Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites
Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites were investigated in detail by using a dynamic rate mode of a high-resolution thermogravimetric analyser (TGA). Two bisphenol A diglycidyl ether-based nanocomposites, EpClay 2 and EpClay 10, containing 2 and 1...
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| Veröffentlicht in: | Polymer degradation and stability 2003, Vol.80 (2), p.383-391 |
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| container_title | Polymer degradation and stability |
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| creator | Gu, Aijuan Liang, Guozheng |
| description | Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites were investigated in detail by using a dynamic rate mode of a high-resolution thermogravimetric analyser (TGA). Two bisphenol A diglycidyl ether-based nanocomposites, EpClay 2 and EpClay 10, containing 2 and 10 phr organic montmorillonite, respectively, were chosen as model systems. The results show that thermal behaviour and kinetic parameters of nanocomposites were dependent on the clay loading and structure of nanocomposites as well as the nature of the purge gas. In both nitrogen and air, EpClay 10 had the lowest initial degradation temperature (Ti), while EpClay 2 had the highest values, however, the combined characteristic of high char yield and low degradation rate temperature of EpClay 10 suggested that it may possess good flame resistance. |
| doi_str_mv | 10.1016/S0141-3910(03)00026-0 |
| format | Article |
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Two bisphenol A diglycidyl ether-based nanocomposites, EpClay 2 and EpClay 10, containing 2 and 10 phr organic montmorillonite, respectively, were chosen as model systems. The results show that thermal behaviour and kinetic parameters of nanocomposites were dependent on the clay loading and structure of nanocomposites as well as the nature of the purge gas. In both nitrogen and air, EpClay 10 had the lowest initial degradation temperature (Ti), while EpClay 2 had the highest values, however, the combined characteristic of high char yield and low degradation rate temperature of EpClay 10 suggested that it may possess good flame resistance.</description><identifier>ISSN: 0141-3910</identifier><identifier>EISSN: 1873-2321</identifier><identifier>DOI: 10.1016/S0141-3910(03)00026-0</identifier><identifier>CODEN: PDSTDW</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Composites ; Dynamic method ; Epoxy ; Exact sciences and technology ; Forms of application and semi-finished materials ; Montmorillonite ; Polymer industry, paints, wood ; Technology of polymers ; TGA</subject><ispartof>Polymer degradation and stability, 2003, Vol.80 (2), p.383-391</ispartof><rights>2003 Elsevier Science Ltd</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-78082d8832d36b3343b23374e2b2fea28f7a908dfe3ae33cb41b209928ab0813</citedby><cites>FETCH-LOGICAL-c368t-78082d8832d36b3343b23374e2b2fea28f7a908dfe3ae33cb41b209928ab0813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0141391003000260$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27900,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14600448$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Gu, Aijuan</creatorcontrib><creatorcontrib>Liang, Guozheng</creatorcontrib><title>Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites</title><title>Polymer degradation and stability</title><description>Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites were investigated in detail by using a dynamic rate mode of a high-resolution thermogravimetric analyser (TGA). Two bisphenol A diglycidyl ether-based nanocomposites, EpClay 2 and EpClay 10, containing 2 and 10 phr organic montmorillonite, respectively, were chosen as model systems. The results show that thermal behaviour and kinetic parameters of nanocomposites were dependent on the clay loading and structure of nanocomposites as well as the nature of the purge gas. In both nitrogen and air, EpClay 10 had the lowest initial degradation temperature (Ti), while EpClay 2 had the highest values, however, the combined characteristic of high char yield and low degradation rate temperature of EpClay 10 suggested that it may possess good flame resistance.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Dynamic method</subject><subject>Epoxy</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Montmorillonite</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><subject>TGA</subject><issn>0141-3910</issn><issn>1873-2321</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkE1PwzAMhiMEEmPwE5B6AcGh4MSly04ITXxJSBzYiUvkpi4E2mQkHWL_nsIQHDn5tfTYlh8h9iWcSJDl6QPIQuY4lXAEeAwAqsxhQ4yknmCuUMlNMfpFtsVOSi8DBMWZHInH-TPHjtqs5qdINfUu-KziZ3p3YRkz8nX26jz3zg6Z2lVyKQtNxovwsTrtgu-7EF3bBu96zjz5YEO3CGno0q7YaqhNvPdTx2J-dTmf3eR399e3s4u73GKp-3yiQataa1Q1lhVigZVCnBSsKtUwKd1MaAq6bhiJEW1VyErBdKo0VaAljsXheu0ihrclp950LlluW_IclskoDUVZghrAszVoY0gpcmMW0XUUV0aC-RJpvkWaL0sG0HyLHMJYHPwcoGSpbSJ569LfcFEOLgs9cOdrjodn3x1Hk6xjb7l2kW1v6uD-ufQJBh2Ihw</recordid><startdate>2003</startdate><enddate>2003</enddate><creator>Gu, Aijuan</creator><creator>Liang, Guozheng</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2003</creationdate><title>Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites</title><author>Gu, Aijuan ; Liang, Guozheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-78082d8832d36b3343b23374e2b2fea28f7a908dfe3ae33cb41b209928ab0813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Dynamic method</topic><topic>Epoxy</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Montmorillonite</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><topic>TGA</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gu, Aijuan</creatorcontrib><creatorcontrib>Liang, Guozheng</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer degradation and stability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gu, Aijuan</au><au>Liang, Guozheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites</atitle><jtitle>Polymer degradation and stability</jtitle><date>2003</date><risdate>2003</risdate><volume>80</volume><issue>2</issue><spage>383</spage><epage>391</epage><pages>383-391</pages><issn>0141-3910</issn><eissn>1873-2321</eissn><coden>PDSTDW</coden><abstract>Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites were investigated in detail by using a dynamic rate mode of a high-resolution thermogravimetric analyser (TGA). 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| ispartof | Polymer degradation and stability, 2003, Vol.80 (2), p.383-391 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Composites Dynamic method Epoxy Exact sciences and technology Forms of application and semi-finished materials Montmorillonite Polymer industry, paints, wood Technology of polymers TGA |
| title | Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites |
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