Synthesis and characterization of fillers of controlled structure based on polyhedral oligomeric silsesquioxane cages and their use in reinforcing siloxane elastomers

Four polyhedral oligomeric silsesquioxane (POSS) cages with vinyl groups were linked to a central siloxane core by hydrosilylation. The goal was to obtain filler particles of sizes between those of the POSS cages themselves and the much larger silica particles typically used to reinforce elastomers....

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Veröffentlicht in:Journal of polymer science. Part B, Polymer physics Polymer physics, 2003-12, Vol.41 (24), p.3314-3323
Hauptverfasser: Pan, Guirong, Mark, James E., Schaefer, Dale W.
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Sprache:eng
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