Thiols as chain transfer agents in free radical polymerization in aqueous solution

The behavior of thiophenol and aliphatic thiols of different structure as chain transfer agents in the polymerization of acrylamide and 1-vinyl-2-pyrrolidone in aqueous solution at 25 °C was studied. Addition of millimolar concentrations of thiols to acrylamide polymerization reduced notably the pol...

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Veröffentlicht in:	Polymer (Guilford) 2003-09, Vol.44 (19), p.5559-5561
Hauptverfasser:	Henrı́quez, C., Bueno, C., Lissi, E.A., Encinas, M.V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Aqueous polymerization Chain transfer Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Thioles
Online-Zugang:	Volltext
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