Stress corrosion cracking of zirconium and Zircaloy-4 in halide aqueous solutions
Zirconium and Zircaloy-4 in 1 M NaCl, 1 M KBr and 1 M KI aqueous solutions were found to be susceptible to stress corrosion cracking (SCC) only at potentials above the pitting potential. In all the tested systems the following steps were found: first electrochemical breakdown of the passive film, fo...
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| Veröffentlicht in: | Corrosion science 2003-11, Vol.45 (11), p.2497-2512 |
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| container_title | Corrosion science |
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| creator | Farina, S.B. Duffo, G.S. Galvele, J.R. |
| description | Zirconium and Zircaloy-4 in 1 M NaCl, 1 M KBr and 1 M KI aqueous solutions were found to be susceptible to stress corrosion cracking (SCC) only at potentials above the pitting potential. In all the tested systems the following steps were found: first electrochemical breakdown of the passive film, followed by intergranular attack due to anodic dissolution assisted by stresses; and finally a fast transgranular propagation. This last step was identified as the “true” SCC process. The analysis of the possible mechanisms involved during this process led to the conclusion that the surface-mobility SCC mechanism can be used to explain the experimental results found in the present work. |
| doi_str_mv | 10.1016/S0010-938X(03)00075-1 |
| format | Article |
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Metallurgy</subject><subject>Pitting</subject><subject>Stress corrosion cracking</subject><subject>Zircaloy-4</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWKs_QchG0cXozWQemZVI8QUFkXYhbkImD41OJzWZEeqvN9MWXboKN_c7995zEDomcEGAFJczAAJJRdnzGdBzACjzhOygEWFllUBWFbto9Ivso4MQ3iOUxp8Repp1XoeApfPeBetaLL2QH7Z9xc7gb-ula22_wKJV-CVWonGrJMO2xW-isUpj8dlr1wccXNN3UR8O0Z4RTdBH23eM5rc388l9Mn28e5hcTxNJC9YldVWU1JCS5sAoM0qUJjZEXtOMKl0wk0GRQSWpTklpalakUKpU1kbVSkpDx-h0M3bpXTwhdHxhg9RNI9rhHp4ySAuWkwjmG1BGg8Frw5feLoRfcQJ8yI-v8-NDOBwoX-fHB93JdoEI0bbxopU2_InzFFKas8hdbTgdzX5Z7XmQVrdSK-u17Lhy9p9NP4q1hcY</recordid><startdate>20031101</startdate><enddate>20031101</enddate><creator>Farina, S.B.</creator><creator>Duffo, G.S.</creator><creator>Galvele, J.R.</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20031101</creationdate><title>Stress corrosion cracking of zirconium and Zircaloy-4 in halide aqueous solutions</title><author>Farina, S.B. ; Duffo, G.S. ; Galvele, J.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-b9673f17350838fda7fc36a5b343de68f406409c3e217fb86207d2cbfdbdccf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>A. Zirconium</topic><topic>Applied sciences</topic><topic>Corrosion</topic><topic>Corrosion tests</topic><topic>Exact sciences and technology</topic><topic>Metals. 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| ispartof | Corrosion science, 2003-11, Vol.45 (11), p.2497-2512 |
| issn | 0010-938X 1879-0496 |
| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | A. Zirconium Applied sciences Corrosion Corrosion tests Exact sciences and technology Metals. Metallurgy Pitting Stress corrosion cracking Zircaloy-4 |
| title | Stress corrosion cracking of zirconium and Zircaloy-4 in halide aqueous solutions |
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