Defluorination of Fluorophenols by a Nonheme Iron(IV)‐Oxo Species: Observation of a New Intermediate Along the Reaction

High‐valent iron(IV)‐oxo intermediates are versatile oxidants in the biotransformation of various substrates by metalloenzymes and catalyze essential reactions for human health as well as in the biodegradation of toxic organic pollutants in the environment. Herein, we report a biomimetic system that...

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Veröffentlicht in:Chemistry : a European journal 2023-07, Vol.29 (39), p.e202300478-n/a
Hauptverfasser: Bagha, Umesh Kumar, Yadav, Rolly, Mokkawes, Thirakorn, Satpathy, Jagnyesh Kumar, Kumar, Devesh, Sastri, Chivukula V., Visser, Sam P.
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Sprache:eng
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