New insights on the adsorption of phenol red dyes from synthetic wastewater using activated carbon/Fe2(MoO4)3
Water shortage is considered as one of the main challenges of human life. A practical solution to this problem is the wastewater treatment. The removal of dyes from wastewaters has received considerable critical attention by researchers due to their high volume and toxicity. In the current research,...
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description | Water shortage is considered as one of the main challenges of human life. A practical solution to this problem is the wastewater treatment. The removal of dyes from wastewaters has received considerable critical attention by researchers due to their high volume and toxicity. In the current research, the adsorption of phenol red dyes from synthetic wastewater using the activated carbon produced from
Mespilus germanica
modified with Fe
2
(MoO
4
)
3
was studied. The proposed adsorbent was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX)/Map, Brunauer–Emmett–Teller (BET), and Raman techniques. The optimal adsorption operating parameters including pH, stirring rate, temperature, dosage of adsorbent, dye initial concentration, and contact time were 3, 500 rpm, 25 °C, 1 g/L, 10 mg/L, and 60 min, respectively. Furthermore, the successful regeneration of the adsorbent for 3 times, using methanol solution as a regeneration medium, denoted its capability in performing adsorption and desorption processes. Equilibrium studies showed that the adsorption of phenol red dyes by activated carbon (AC)/Fe
2
(MoO
4
)
3
was desirable and physical and the experimental data were fitted well by the Freundlich model. In addition, the kinetic behavior of the current adsorption process was well described by the pseudo-second-order kinetic model, while thermodynamic calculations showed that the process was exothermic and spontaneous. |
doi_str_mv | 10.1007/s10661-023-11178-w |
format | Article |
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Mespilus germanica
modified with Fe
2
(MoO
4
)
3
was studied. The proposed adsorbent was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX)/Map, Brunauer–Emmett–Teller (BET), and Raman techniques. The optimal adsorption operating parameters including pH, stirring rate, temperature, dosage of adsorbent, dye initial concentration, and contact time were 3, 500 rpm, 25 °C, 1 g/L, 10 mg/L, and 60 min, respectively. Furthermore, the successful regeneration of the adsorbent for 3 times, using methanol solution as a regeneration medium, denoted its capability in performing adsorption and desorption processes. Equilibrium studies showed that the adsorption of phenol red dyes by activated carbon (AC)/Fe
2
(MoO
4
)
3
was desirable and physical and the experimental data were fitted well by the Freundlich model. In addition, the kinetic behavior of the current adsorption process was well described by the pseudo-second-order kinetic model, while thermodynamic calculations showed that the process was exothermic and spontaneous.</description><identifier>ISSN: 0167-6369</identifier><identifier>EISSN: 1573-2959</identifier><identifier>DOI: 10.1007/s10661-023-11178-w</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Activated carbon ; Adsorbents ; Adsorption ; Atmospheric Protection/Air Quality Control/Air Pollution ; Carbon ; Color removal ; desorption ; Dyes ; Earth and Environmental Science ; Ecology ; Ecotoxicology ; Electron microscopes ; Energy dispersive X ray analysis ; Environment ; Environmental Management ; Environmental monitoring ; Environmental science ; Fourier transform infrared spectroscopy ; Fourier transforms ; heat production ; humans ; kinetics ; Mespilus germanica ; methanol ; Monitoring/Environmental Analysis ; Phenols ; phenolsulfonphthalein ; Regeneration ; Scanning electron microscopy ; sorption isotherms ; temperature ; Toxicity ; wastewater ; Wastewater treatment ; Water shortages ; X ray analysis ; X rays ; X-ray diffraction ; X-ray spectroscopy</subject><ispartof>Environmental monitoring and assessment, 2023-05, Vol.195 (5), p.574-574, Article 574</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-7634ea61ca111fd9140cdbc21ff4a7c991147ccf2e9f1abd77e3616eccefef683</citedby><cites>FETCH-LOGICAL-c385t-7634ea61ca111fd9140cdbc21ff4a7c991147ccf2e9f1abd77e3616eccefef683</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10661-023-11178-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10661-023-11178-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Nobakht, Alireza</creatorcontrib><creatorcontrib>Jafari, Dariush</creatorcontrib><creatorcontrib>Esfandyari, Morteza</creatorcontrib><title>New insights on the adsorption of phenol red dyes from synthetic wastewater using activated carbon/Fe2(MoO4)3</title><title>Environmental monitoring and assessment</title><addtitle>Environ Monit Assess</addtitle><description>Water shortage is considered as one of the main challenges of human life. A practical solution to this problem is the wastewater treatment. The removal of dyes from wastewaters has received considerable critical attention by researchers due to their high volume and toxicity. In the current research, the adsorption of phenol red dyes from synthetic wastewater using the activated carbon produced from
Mespilus germanica
modified with Fe
2
(MoO
4
)
3
was studied. The proposed adsorbent was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX)/Map, Brunauer–Emmett–Teller (BET), and Raman techniques. The optimal adsorption operating parameters including pH, stirring rate, temperature, dosage of adsorbent, dye initial concentration, and contact time were 3, 500 rpm, 25 °C, 1 g/L, 10 mg/L, and 60 min, respectively. Furthermore, the successful regeneration of the adsorbent for 3 times, using methanol solution as a regeneration medium, denoted its capability in performing adsorption and desorption processes. Equilibrium studies showed that the adsorption of phenol red dyes by activated carbon (AC)/Fe
2
(MoO
4
)
3
was desirable and physical and the experimental data were fitted well by the Freundlich model. In addition, the kinetic behavior of the current adsorption process was well described by the pseudo-second-order kinetic model, while thermodynamic calculations showed that the process was exothermic and spontaneous.</description><subject>Activated carbon</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Carbon</subject><subject>Color removal</subject><subject>desorption</subject><subject>Dyes</subject><subject>Earth and Environmental Science</subject><subject>Ecology</subject><subject>Ecotoxicology</subject><subject>Electron microscopes</subject><subject>Energy dispersive X ray analysis</subject><subject>Environment</subject><subject>Environmental Management</subject><subject>Environmental monitoring</subject><subject>Environmental science</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fourier transforms</subject><subject>heat production</subject><subject>humans</subject><subject>kinetics</subject><subject>Mespilus germanica</subject><subject>methanol</subject><subject>Monitoring/Environmental Analysis</subject><subject>Phenols</subject><subject>phenolsulfonphthalein</subject><subject>Regeneration</subject><subject>Scanning electron microscopy</subject><subject>sorption isotherms</subject><subject>temperature</subject><subject>Toxicity</subject><subject>wastewater</subject><subject>Wastewater treatment</subject><subject>Water shortages</subject><subject>X ray analysis</subject><subject>X rays</subject><subject>X-ray diffraction</subject><subject>X-ray 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monitoring and assessment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nobakht, Alireza</au><au>Jafari, Dariush</au><au>Esfandyari, Morteza</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New insights on the adsorption of phenol red dyes from synthetic wastewater using activated carbon/Fe2(MoO4)3</atitle><jtitle>Environmental monitoring and assessment</jtitle><stitle>Environ Monit Assess</stitle><date>2023-05-01</date><risdate>2023</risdate><volume>195</volume><issue>5</issue><spage>574</spage><epage>574</epage><pages>574-574</pages><artnum>574</artnum><issn>0167-6369</issn><eissn>1573-2959</eissn><abstract>Water shortage is considered as one of the main challenges of human life. A practical solution to this problem is the wastewater treatment. The removal of dyes from wastewaters has received considerable critical attention by researchers due to their high volume and toxicity. In the current research, the adsorption of phenol red dyes from synthetic wastewater using the activated carbon produced from
Mespilus germanica
modified with Fe
2
(MoO
4
)
3
was studied. The proposed adsorbent was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX)/Map, Brunauer–Emmett–Teller (BET), and Raman techniques. The optimal adsorption operating parameters including pH, stirring rate, temperature, dosage of adsorbent, dye initial concentration, and contact time were 3, 500 rpm, 25 °C, 1 g/L, 10 mg/L, and 60 min, respectively. Furthermore, the successful regeneration of the adsorbent for 3 times, using methanol solution as a regeneration medium, denoted its capability in performing adsorption and desorption processes. Equilibrium studies showed that the adsorption of phenol red dyes by activated carbon (AC)/Fe
2
(MoO
4
)
3
was desirable and physical and the experimental data were fitted well by the Freundlich model. In addition, the kinetic behavior of the current adsorption process was well described by the pseudo-second-order kinetic model, while thermodynamic calculations showed that the process was exothermic and spontaneous.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10661-023-11178-w</doi><tpages>1</tpages></addata></record> |
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subjects | Activated carbon Adsorbents Adsorption Atmospheric Protection/Air Quality Control/Air Pollution Carbon Color removal desorption Dyes Earth and Environmental Science Ecology Ecotoxicology Electron microscopes Energy dispersive X ray analysis Environment Environmental Management Environmental monitoring Environmental science Fourier transform infrared spectroscopy Fourier transforms heat production humans kinetics Mespilus germanica methanol Monitoring/Environmental Analysis Phenols phenolsulfonphthalein Regeneration Scanning electron microscopy sorption isotherms temperature Toxicity wastewater Wastewater treatment Water shortages X ray analysis X rays X-ray diffraction X-ray spectroscopy |
title | New insights on the adsorption of phenol red dyes from synthetic wastewater using activated carbon/Fe2(MoO4)3 |
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