Study on the synthesis of brominated epoxy resins
The GC/MS/Py method, thermogravimetric analysis (TG), MALDI‐TOF spectrometry, and IR spectra were utilized to investigate structures and thermal stability of brominated epoxy resins synthesized in the reaction of epichlorohydrin (ECH) and tetrabromobisphenol A (TBBA), with varied molar rates of mono...
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| Veröffentlicht in: | Journal of applied polymer science 2003-12, Vol.90 (11), p.3122-3134 |
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| container_issue | 11 |
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| container_title | Journal of applied polymer science |
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| creator | KROL, Piotr KROL, Bozena DZIWINSKI, Euzebiusz |
| description | The GC/MS/Py method, thermogravimetric analysis (TG), MALDI‐TOF spectrometry, and IR spectra were utilized to investigate structures and thermal stability of brominated epoxy resins synthesized in the reaction of epichlorohydrin (ECH) and tetrabromobisphenol A (TBBA), with varied molar rates of monomers and varied condensation temperatures. A Rheotest viscometer was employed to test rheological properties of the resins, while their mechanical properties were determined after hardening with phthalic anhydride. The research work revealed that the optimum synthesis conditions were ECH : TBBA = 5 : 1, and the condensation temperature reasonably low (e.g., 40°C). The basic properties of the synthesized resins were found to be comparable to those of the commercial product D.E.R. 542 offered by Dow Plastics. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3122–3134, 2003 |
| doi_str_mv | 10.1002/app.13051 |
| format | Article |
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A Rheotest viscometer was employed to test rheological properties of the resins, while their mechanical properties were determined after hardening with phthalic anhydride. The research work revealed that the optimum synthesis conditions were ECH : TBBA = 5 : 1, and the condensation temperature reasonably low (e.g., 40°C). The basic properties of the synthesized resins were found to be comparable to those of the commercial product D.E.R. 542 offered by Dow Plastics. © 2003 Wiley Periodicals, Inc. 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J Appl Polym Sci 90: 3122–3134, 2003</description><subject>Applied sciences</subject><subject>Chemical properties</subject><subject>Exact sciences and technology</subject><subject>MALDI</subject><subject>mechanical properties</subject><subject>Polymer industry, paints, wood</subject><subject>Properties and testing</subject><subject>Technology of polymers</subject><subject>thermal properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAQhS0EEqUw8A-ygMSQ1hfHcTxWFbRIpVSiEmyW4zoikCbBl4rm3-PSAhPLveHe-3T3CLkEOgBKo6FumgEwyuGI9IBKEcZJlB6Tnt9BmErJT8kZ4hulAJwmPQJP7WbVBXUVtK82wK7yggUGdR5krl4XlW7tKrBNve0C5zcVnpOTXJdoLw7aJ8u72-V4Gs4eJ_fj0Sw0LEkglH4AF0nMqBBMxjqzkoLlMk1yASsmZGr8BUYLK2WUC5vHmgsdZRnLuKGsT6732MbVHxuLrVoXaGxZ6srWG1RR6l-QaeyNN3ujcTWis7lqXLHWrlNA1a4T5TtR351479UBqtHoMne6MgX-BXjkkXLHHO59n0Vpu_-BarRY_JDDfaLA1m5_E9q9q0QwwdXzfKJ4PIb05WGupuwLf5Z9Iw</recordid><startdate>20031209</startdate><enddate>20031209</enddate><creator>KROL, Piotr</creator><creator>KROL, Bozena</creator><creator>DZIWINSKI, Euzebiusz</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20031209</creationdate><title>Study on the synthesis of brominated epoxy resins</title><author>KROL, Piotr ; KROL, Bozena ; DZIWINSKI, Euzebiusz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3661-9661157643077394abe901e5986f71d3798c506ca7e992f7ef4a57a2bb3b5c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>Chemical properties</topic><topic>Exact sciences and technology</topic><topic>MALDI</topic><topic>mechanical properties</topic><topic>Polymer industry, paints, wood</topic><topic>Properties and testing</topic><topic>Technology of polymers</topic><topic>thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KROL, Piotr</creatorcontrib><creatorcontrib>KROL, Bozena</creatorcontrib><creatorcontrib>DZIWINSKI, Euzebiusz</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KROL, Piotr</au><au>KROL, Bozena</au><au>DZIWINSKI, Euzebiusz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study on the synthesis of brominated epoxy resins</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Chemical properties Exact sciences and technology MALDI mechanical properties Polymer industry, paints, wood Properties and testing Technology of polymers thermal properties |
| title | Study on the synthesis of brominated epoxy resins |
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