Numerical Simulation and Experimental Study of Methyl Ammonium Bismuth Iodide Absorber Layer Based Lead Free Perovskite Solar Cells
In the past few years, there has been a significant increase in the development and production of perovskite or perovskite‐like materials that do not contain lead (Pb) for the purpose of constructing solar cells. The development and testing of lead‐free perovskite‐like structures for solar cells is...
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| Veröffentlicht in: | Chemistry : a European journal 2023-06, Vol.29 (35), p.e202300513-n/a |
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| creator | Ahmad, Khursheed Quasim Khan, Mohd Alsulmi, Ali Kim, Haekyoung |
| description | In the past few years, there has been a significant increase in the development and production of perovskite or perovskite‐like materials that do not contain lead (Pb) for the purpose of constructing solar cells. The development and testing of lead‐free perovskite‐like structures for solar cells is crucial. In this study, we used the solar cell capacitance software (SCAPS) to simulate perovskite solar cells based on methyl ammonium bismuth iodide (MA3Bi2I9). The electron‐transport layer, hole‐transport layer, and absorber layer thickness were optimized using SCAPS. The simulated perovskite solar cells (FTO/TiO2/MA3Bi2I9/spiro‐OMeTAD/Au) performed well with a power conversion efficiency of 14.07 % and a reasonable open circuit voltage of 1.34 V, using the optimized conditions determined by SCAPS. Additionally, we conducted experiments to fabricate perovskite solar cells under controlled humidity, which showed a power conversion efficiency of 1.31 %.
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| doi_str_mv | 10.1002/chem.202300513 |
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SCAPS<? >1D simulation software was to investigate the simulation of lead‐free methyl ammonium bismuth iodide (MA3Bi2I9) based perovskite solar cells. The study examined various electron and hole transport layers and optimized the thickness of each layer using the software. The results showed a power conversion efficiency of 14.07 % via the simulation software, and reasonable efficiency and open circuit voltage in the fabricated MA3Bi2I9 based perovskite solar cells.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.202300513</identifier><identifier>PMID: 37029556</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Absorbers ; Ammonium ; Bismuth ; Capacitance ; Chemistry ; Energy conversion efficiency ; Iodides ; Lead free ; lead-free perovskite absorber layer ; MA3Bi2I9 ; Mathematical models ; Open circuit voltage ; perovskite solar cells ; Perovskites ; Photovoltaic cells ; SCAPS_1D ; Simulation ; Solar cells ; Thickness ; Titanium dioxide</subject><ispartof>Chemistry : a European journal, 2023-06, Vol.29 (35), p.e202300513-n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><rights>2023 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3733-baa14fafcfe1665b5c0f3e50fffbd1ae555d3a994f26118457b7e0b5e6f67313</citedby><cites>FETCH-LOGICAL-c3733-baa14fafcfe1665b5c0f3e50fffbd1ae555d3a994f26118457b7e0b5e6f67313</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.202300513$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.202300513$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37029556$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ahmad, Khursheed</creatorcontrib><creatorcontrib>Quasim Khan, Mohd</creatorcontrib><creatorcontrib>Alsulmi, Ali</creatorcontrib><creatorcontrib>Kim, Haekyoung</creatorcontrib><title>Numerical Simulation and Experimental Study of Methyl Ammonium Bismuth Iodide Absorber Layer Based Lead Free Perovskite Solar Cells</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>In the past few years, there has been a significant increase in the development and production of perovskite or perovskite‐like materials that do not contain lead (Pb) for the purpose of constructing solar cells. The development and testing of lead‐free perovskite‐like structures for solar cells is crucial. In this study, we used the solar cell capacitance software (SCAPS) to simulate perovskite solar cells based on methyl ammonium bismuth iodide (MA3Bi2I9). The electron‐transport layer, hole‐transport layer, and absorber layer thickness were optimized using SCAPS. The simulated perovskite solar cells (FTO/TiO2/MA3Bi2I9/spiro‐OMeTAD/Au) performed well with a power conversion efficiency of 14.07 % and a reasonable open circuit voltage of 1.34 V, using the optimized conditions determined by SCAPS. Additionally, we conducted experiments to fabricate perovskite solar cells under controlled humidity, which showed a power conversion efficiency of 1.31 %.
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SCAPS<? >1D simulation software was to investigate the simulation of lead‐free methyl ammonium bismuth iodide (MA3Bi2I9) based perovskite solar cells. The study examined various electron and hole transport layers and optimized the thickness of each layer using the software. The results showed a power conversion efficiency of 14.07 % via the simulation software, and reasonable efficiency and open circuit voltage in the fabricated MA3Bi2I9 based perovskite solar cells.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>37029556</pmid><doi>10.1002/chem.202300513</doi><tpages>10</tpages></addata></record> |
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| subjects | Absorbers Ammonium Bismuth Capacitance Chemistry Energy conversion efficiency Iodides Lead free lead-free perovskite absorber layer MA3Bi2I9 Mathematical models Open circuit voltage perovskite solar cells Perovskites Photovoltaic cells SCAPS_1D Simulation Solar cells Thickness Titanium dioxide |
| title | Numerical Simulation and Experimental Study of Methyl Ammonium Bismuth Iodide Absorber Layer Based Lead Free Perovskite Solar Cells |
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