Solid-phase precipitation of CdTe nanoparticles in glass

Growth of CdTe nanoparticles in glass is studied through the analysis of optical absorption spectroscopy with the help of a quantized state effective mass model. Glass includes nanoparticles with an initial size of ∼1.6 nm on cooling to room temperature from the melt at ∼1000 °C. Particles form by h...

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Veröffentlicht in:Phys. Status Solidi (b). Vol. 236, no. 3, pp. 694-701. 2003 no. 3, pp. 694-701. 2003, 2003-04, Vol.236 (3), p.694-701
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description Growth of CdTe nanoparticles in glass is studied through the analysis of optical absorption spectroscopy with the help of a quantized state effective mass model. Glass includes nanoparticles with an initial size of ∼1.6 nm on cooling to room temperature from the melt at ∼1000 °C. Particles form by heterogeneous nucleation followed by diffusion‐limited growth. The narrowest particle size dispersion of 15% is obtained for an average radius of ∼2.28 nm at the end of heat treatment at 600 °C for 4.5 h. The magnitude of the absorption related to the number of particles is low due to the oxidation of Te. A combinative use of Arrhenius plots and the model yields an activation energy for diffusion of ∼170 kJ mol–1.
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subjects 66.30.Pa
78.40.Pg
78.67.Bf
78.67.Hc
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Diffusion in nanoscale solids
Diffusion in solids
Exact sciences and technology
Nanocrystals and nanoparticles
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures
Physics
Transport properties of condensed matter (nonelectronic)
title Solid-phase precipitation of CdTe nanoparticles in glass
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