Palladium-Catalyzed Hydroalkoxycarbonylation and Hydroxycarbonylation of Cyclopent-3-en-1-ols: Divergent Synthesis of Bridged Cyclic Lactones and β,γ-Unsaturated Carboxylic Acids

Herein, we report a palladium-catalyzed hydroalkoxycarbonylation and hydroxycarbonylation of cyclopent-3-en-1-ols to form bridged bicyclic lactones and β,γ-unsaturated carboxylic acid. The divergent reactivity of cyclopent-3-en-1-ols is mainly tuned by the palladium catalyst and ligands. The reactio...

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Veröffentlicht in:	Organic letters 2023-04, Vol.25 (15), p.2571-2576
Hauptverfasser:	Chen, Ming, Li, Yang, Guan, Zheng-Hui
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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