Synthesis and Growth Kinetics of Monodispersive Indium Hydrate Particles
Nano‐ or submicron In(OH)3 and In2O3 particles of different morphologies were synthesized from a nitrate solution by a homogeneous precipitation process. By using X‐ray diffractometer, thermogravimetric analysis, transmission and scanning electron microscopes, and inductively coupled plasma‐optical...
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| Veröffentlicht in: | Journal of the American Ceramic Society 2006-02, Vol.89 (2), p.527-533 |
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| creator | Lin, Sung-En Wei, Wen-Cheng J. |
| description | Nano‐ or submicron In(OH)3 and In2O3 particles of different morphologies were synthesized from a nitrate solution by a homogeneous precipitation process. By using X‐ray diffractometer, thermogravimetric analysis, transmission and scanning electron microscopes, and inductively coupled plasma‐optical emission spectrometry, the properties of particle growth were analyzed. The results indicated that the kinetics of the hydrolysis reaction of In3+ was a zero‐order reaction with an activation energy of 128 kJ/mol, which implied that the reaction was controlled by the decomposition kinetic of urea additive. The growth anisotropic of particles, pH value of reaction solutions, residual In3+ concentration relative to aging time with different temperatures and starting concentrations were reported in this study. Calcination of the hydrate to form In2O3 particles between 300° and 900°C did not greatly change the morphologies of the particles. |
| doi_str_mv | 10.1111/j.1551-2916.2005.00776.x |
| format | Article |
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By using X‐ray diffractometer, thermogravimetric analysis, transmission and scanning electron microscopes, and inductively coupled plasma‐optical emission spectrometry, the properties of particle growth were analyzed. The results indicated that the kinetics of the hydrolysis reaction of In3+ was a zero‐order reaction with an activation energy of 128 kJ/mol, which implied that the reaction was controlled by the decomposition kinetic of urea additive. The growth anisotropic of particles, pH value of reaction solutions, residual In3+ concentration relative to aging time with different temperatures and starting concentrations were reported in this study. Calcination of the hydrate to form In2O3 particles between 300° and 900°C did not greatly change the morphologies of the particles.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1551-2916.2005.00776.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Malden, USA: Blackwell Science Inc</publisher><subject>Anisotropy ; Ceramics ; Chemistry ; Colloidal state and disperse state ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; General and physical chemistry ; Hydrates ; Indium ; Indium oxides ; Kinetics ; Materials science ; Morphology ; Nanopowders ; Nanoscale materials and structures: fabrication and characterization ; Nanostructure ; Physics ; Powders ; Reaction kinetics ; Scanning electron microscopy ; Scientific imaging</subject><ispartof>Journal of the American Ceramic Society, 2006-02, Vol.89 (2), p.527-533</ispartof><rights>2007 INIST-CNRS</rights><rights>Copyright American Ceramic Society Feb 2006</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5556-89671f3ab8ee4c9020bc9494bfd22410214f745506b67f8fd12f7e03cd0651ae3</citedby><cites>FETCH-LOGICAL-c5556-89671f3ab8ee4c9020bc9494bfd22410214f745506b67f8fd12f7e03cd0651ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fj.1551-2916.2005.00776.x$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fj.1551-2916.2005.00776.x$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17512126$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lin, Sung-En</creatorcontrib><creatorcontrib>Wei, Wen-Cheng J.</creatorcontrib><title>Synthesis and Growth Kinetics of Monodispersive Indium Hydrate Particles</title><title>Journal of the American Ceramic Society</title><description>Nano‐ or submicron In(OH)3 and In2O3 particles of different morphologies were synthesized from a nitrate solution by a homogeneous precipitation process. By using X‐ray diffractometer, thermogravimetric analysis, transmission and scanning electron microscopes, and inductively coupled plasma‐optical emission spectrometry, the properties of particle growth were analyzed. The results indicated that the kinetics of the hydrolysis reaction of In3+ was a zero‐order reaction with an activation energy of 128 kJ/mol, which implied that the reaction was controlled by the decomposition kinetic of urea additive. The growth anisotropic of particles, pH value of reaction solutions, residual In3+ concentration relative to aging time with different temperatures and starting concentrations were reported in this study. Calcination of the hydrate to form In2O3 particles between 300° and 900°C did not greatly change the morphologies of the particles.</description><subject>Anisotropy</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Hydrates</subject><subject>Indium</subject><subject>Indium oxides</subject><subject>Kinetics</subject><subject>Materials science</subject><subject>Morphology</subject><subject>Nanopowders</subject><subject>Nanoscale materials and structures: fabrication and characterization</subject><subject>Nanostructure</subject><subject>Physics</subject><subject>Powders</subject><subject>Reaction kinetics</subject><subject>Scanning electron microscopy</subject><subject>Scientific imaging</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqNkV1v0zAUhi0EEmXwHywkEDfJbMdfuUKjGu1GGEgMcWm5zrHmkibFTln773HWaUhcoPnm2DrPeY6sFyFMSUnzOV2XVAhasJrKkhEiSkKUkuX-CZo9NJ6iGSGEFUoz8hy9SGmdn7TWfIaW3w79eAMpJGz7Fi_icDve4E-hhzG4hAePPw_90Ia0hZjCb8AXfRt2G7w8tNGOgL_amMEO0kv0zNsuwav7eoK-fzy_ni-L5sviYn7WFE4IIQtdS0V9ZVcagLuaMLJyNa_5yreMcUoY5V5xIYhcSeW1bynzCkjlWiIFtVCdoLdH7zYOv3aQRrMJyUHX2R6GXTJM1bLSkj8KZFzqDL77L0iJZlRpyqqMvv4HXQ-72Of_mozUQikyLdZHyMUhpQjebGPY2HjIJjNlZtZmisZM0ZgpM3OXmdnn0Tf3fpuc7Xy0vQvp77wSlFEmM_f-yN2GDg6P9pvLs_n53T0biqMhpBH2DwYbfxqpKiXMj6uF-dDIxXVDG3NV_QGla7dQ</recordid><startdate>200602</startdate><enddate>200602</enddate><creator>Lin, Sung-En</creator><creator>Wei, Wen-Cheng J.</creator><general>Blackwell Science Inc</general><general>Blackwell</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200602</creationdate><title>Synthesis and Growth Kinetics of Monodispersive Indium Hydrate Particles</title><author>Lin, Sung-En ; Wei, Wen-Cheng J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5556-89671f3ab8ee4c9020bc9494bfd22410214f745506b67f8fd12f7e03cd0651ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Anisotropy</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Hydrates</topic><topic>Indium</topic><topic>Indium oxides</topic><topic>Kinetics</topic><topic>Materials science</topic><topic>Morphology</topic><topic>Nanopowders</topic><topic>Nanoscale materials and structures: fabrication and characterization</topic><topic>Nanostructure</topic><topic>Physics</topic><topic>Powders</topic><topic>Reaction kinetics</topic><topic>Scanning electron microscopy</topic><topic>Scientific imaging</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Sung-En</creatorcontrib><creatorcontrib>Wei, Wen-Cheng J.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Sung-En</au><au>Wei, Wen-Cheng J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Growth Kinetics of Monodispersive Indium Hydrate Particles</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2006-02</date><risdate>2006</risdate><volume>89</volume><issue>2</issue><spage>527</spage><epage>533</epage><pages>527-533</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>Nano‐ or submicron In(OH)3 and In2O3 particles of different morphologies were synthesized from a nitrate solution by a homogeneous precipitation process. By using X‐ray diffractometer, thermogravimetric analysis, transmission and scanning electron microscopes, and inductively coupled plasma‐optical emission spectrometry, the properties of particle growth were analyzed. The results indicated that the kinetics of the hydrolysis reaction of In3+ was a zero‐order reaction with an activation energy of 128 kJ/mol, which implied that the reaction was controlled by the decomposition kinetic of urea additive. The growth anisotropic of particles, pH value of reaction solutions, residual In3+ concentration relative to aging time with different temperatures and starting concentrations were reported in this study. Calcination of the hydrate to form In2O3 particles between 300° and 900°C did not greatly change the morphologies of the particles.</abstract><cop>Malden, USA</cop><pub>Blackwell Science Inc</pub><doi>10.1111/j.1551-2916.2005.00776.x</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Anisotropy Ceramics Chemistry Colloidal state and disperse state Cross-disciplinary physics: materials science rheology Exact sciences and technology General and physical chemistry Hydrates Indium Indium oxides Kinetics Materials science Morphology Nanopowders Nanoscale materials and structures: fabrication and characterization Nanostructure Physics Powders Reaction kinetics Scanning electron microscopy Scientific imaging |
| title | Synthesis and Growth Kinetics of Monodispersive Indium Hydrate Particles |
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