Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe() N-heterocyclic carbene complexes

Steady state and ultrafast spectroscopy on [Fe III (phtmeimb) 2 ]PF 6 (phtmeimb = phenyl(tris(3-methylimidazol-2-ylidene))borate) was performed over a broad range of temperatures. The intramolecular deactivation dynamics of the luminescent doublet ligand-to-metal charge-transfer ( 2 LMCT) state was...

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Veröffentlicht in:	Chemical science (Cambridge) 2023-03, Vol.14 (13), p.3569-3579
Hauptverfasser:	Rosemann, Nils W, Lindh, Linnea, Bolaño Losada, Iria, Kaufhold, Simon, Prakash, Om, Ilic, Aleksandra, Schwarz, Jesper, Wärnmark, Kenneth, Chábera, Pavel, Yartsev, Arkady, Persson, Petter
Format:	Artikel
Sprache:	eng
Schlagworte:	Charge transfer Chemical Sciences Chemistry Deactivation Disproportionation Kemi Natural Sciences Naturvetenskap Separation Teoretisk kemi Theoretical Chemistry
Online-Zugang:	Volltext
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