Process–structure–property relationships of erodable polymeric biomaterials: II—long range order in poly(desaminotyrosyl arylates)
The long-range order of some bioerodable polyesteramides based on a desaminotyrosyl [Thermochim Acta 396 (2003) 141; Polym Adv Technol 13 (2002) 926; J Am Chem Soc 119 (1997) 4553] diol monomer has been investigated. The order is mesogenic, best described as a ‘condis crystal’ or smectic-like. In al...
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| Veröffentlicht in: | Polymer (Guilford) 2003-09, Vol.44 (19), p.6033-6042 |
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| container_title | Polymer (Guilford) |
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| creator | Jaffe, Michael Ophir, Zohar Collins, George Recber, Ali Yoo, Seung-uk Rafalko, Joseph J. |
| description | The long-range order of some bioerodable polyesteramides based on a desaminotyrosyl [Thermochim Acta 396 (2003) 141; Polym Adv Technol 13 (2002) 926; J Am Chem Soc 119 (1997) 4553] diol monomer has been investigated. The order is mesogenic, best described as a ‘condis crystal’ or smectic-like. In all cases where long-range order is present, ordered H bonds between amide groups are observed. The order stabilizes the polymer to dimensional change and mechanical relaxation under biorelevant conditions. |
| doi_str_mv | 10.1016/S0032-3861(03)00559-7 |
| format | Article |
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| ispartof | Polymer (Guilford), 2003-09, Vol.44 (19), p.6033-6042 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Exact sciences and technology FT-IR Hydrogen bonding Mesogenic bioerodable polyesteramide Organic polymers Physicochemistry of polymers Properties and characterization Structure, morphology and analysis |
| title | Process–structure–property relationships of erodable polymeric biomaterials: II—long range order in poly(desaminotyrosyl arylates) |
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