Electrochemical stability and conductivity enhancement of composite polymer electrolytes
The electrochemical stability behavior of the composite polymer electrolytes obtained by adding a fine Al 2O 3 powder (activated acidic, neutral, and basic) with a diameter of 5.8 nm to the poly(ethylene oxide) (PEO)–LiClO 4 is described. The strong hydrogen bond between the surface group of Al 2O 3...
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| Veröffentlicht in: | Solid state ionics 2003-03, Vol.159 (1), p.111-119 |
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| container_title | Solid state ionics |
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| creator | Park, Chang Hyun Kim, Dong Won Prakash, Jai Sun, Yang-Kook |
| description | The electrochemical stability behavior of the composite polymer electrolytes obtained by adding a fine Al
2O
3 powder (activated acidic, neutral, and basic) with a diameter of 5.8 nm to the poly(ethylene oxide) (PEO)–LiClO
4 is described. The strong hydrogen bond between the surface group of Al
2O
3 and lithium salt anion prevents the decomposition of lithium salt anion. An enhancement of the ionic conductivity for the composite polymer electrolytes prepared with Al
2O
3 and BaTiO
3 is described in terms of a reduction of crystallinity and an increase of charge carrier concentration. |
| doi_str_mv | 10.1016/S0167-2738(03)00025-0 |
| format | Article |
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2O
3 powder (activated acidic, neutral, and basic) with a diameter of 5.8 nm to the poly(ethylene oxide) (PEO)–LiClO
4 is described. The strong hydrogen bond between the surface group of Al
2O
3 and lithium salt anion prevents the decomposition of lithium salt anion. An enhancement of the ionic conductivity for the composite polymer electrolytes prepared with Al
2O
3 and BaTiO
3 is described in terms of a reduction of crystallinity and an increase of charge carrier concentration.</description><identifier>ISSN: 0167-2738</identifier><identifier>EISSN: 1872-7689</identifier><identifier>DOI: 10.1016/S0167-2738(03)00025-0</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Composite polymer electrolyte ; Electrochemical stability ; Inorganic filler ; Ionic conductivity ; Lithium battery</subject><ispartof>Solid state ionics, 2003-03, Vol.159 (1), p.111-119</ispartof><rights>2003 Elsevier Science B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c404t-c419b255f85e176a636769b2b861f035f10e8a42cc6b057c28a1f2bd988441b73</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0167-2738(03)00025-0$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27907,27908,45978</link.rule.ids></links><search><creatorcontrib>Park, Chang Hyun</creatorcontrib><creatorcontrib>Kim, Dong Won</creatorcontrib><creatorcontrib>Prakash, Jai</creatorcontrib><creatorcontrib>Sun, Yang-Kook</creatorcontrib><title>Electrochemical stability and conductivity enhancement of composite polymer electrolytes</title><title>Solid state ionics</title><description>The electrochemical stability behavior of the composite polymer electrolytes obtained by adding a fine Al
2O
3 powder (activated acidic, neutral, and basic) with a diameter of 5.8 nm to the poly(ethylene oxide) (PEO)–LiClO
4 is described. The strong hydrogen bond between the surface group of Al
2O
3 and lithium salt anion prevents the decomposition of lithium salt anion. An enhancement of the ionic conductivity for the composite polymer electrolytes prepared with Al
2O
3 and BaTiO
3 is described in terms of a reduction of crystallinity and an increase of charge carrier concentration.</description><subject>Composite polymer electrolyte</subject><subject>Electrochemical stability</subject><subject>Inorganic filler</subject><subject>Ionic conductivity</subject><subject>Lithium battery</subject><issn>0167-2738</issn><issn>1872-7689</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LxDAQxYMouK5-BKEn0UM1SdskPYks6x9Y8KCCt5CmUzbSNjXJLvTbm27Fq5cZePPeg_khdEnwLcGE3b3FwVPKM3GNsxuMMS1SfIQWRHCacibKY7T4s5yiM--_oollgi3Q57oFHZzVW-iMVm3ig6pMa8KYqL5OtO3rnQ5mPwnQb1WvoYM-JLaJt26w3gRIBtuOHbgE5q52DODP0UmjWg8Xv3uJPh7X76vndPP69LJ62KQ6x3mIk5QVLYpGFEA4UyxjnEWlEow0OCsagkGonGrNKlxwTYUiDa3qUog8JxXPluhq7h2c_d6BD7IzXkPbqh7szkvKS5oRjKOxmI3aWe8dNHJwplNulATLiaM8cJQTJIkzeeAop9z9nIP4xd6Ak14biBxq4-K7srbmn4YfQOZ7lA</recordid><startdate>20030301</startdate><enddate>20030301</enddate><creator>Park, Chang Hyun</creator><creator>Kim, Dong Won</creator><creator>Prakash, Jai</creator><creator>Sun, Yang-Kook</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20030301</creationdate><title>Electrochemical stability and conductivity enhancement of composite polymer electrolytes</title><author>Park, Chang Hyun ; Kim, Dong Won ; Prakash, Jai ; Sun, Yang-Kook</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c404t-c419b255f85e176a636769b2b861f035f10e8a42cc6b057c28a1f2bd988441b73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Composite polymer electrolyte</topic><topic>Electrochemical stability</topic><topic>Inorganic filler</topic><topic>Ionic conductivity</topic><topic>Lithium battery</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Park, Chang Hyun</creatorcontrib><creatorcontrib>Kim, Dong Won</creatorcontrib><creatorcontrib>Prakash, Jai</creatorcontrib><creatorcontrib>Sun, Yang-Kook</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Park, Chang Hyun</au><au>Kim, Dong Won</au><au>Prakash, Jai</au><au>Sun, Yang-Kook</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical stability and conductivity enhancement of composite polymer electrolytes</atitle><jtitle>Solid state ionics</jtitle><date>2003-03-01</date><risdate>2003</risdate><volume>159</volume><issue>1</issue><spage>111</spage><epage>119</epage><pages>111-119</pages><issn>0167-2738</issn><eissn>1872-7689</eissn><abstract>The electrochemical stability behavior of the composite polymer electrolytes obtained by adding a fine Al
2O
3 powder (activated acidic, neutral, and basic) with a diameter of 5.8 nm to the poly(ethylene oxide) (PEO)–LiClO
4 is described. The strong hydrogen bond between the surface group of Al
2O
3 and lithium salt anion prevents the decomposition of lithium salt anion. An enhancement of the ionic conductivity for the composite polymer electrolytes prepared with Al
2O
3 and BaTiO
3 is described in terms of a reduction of crystallinity and an increase of charge carrier concentration.</abstract><pub>Elsevier B.V</pub><doi>10.1016/S0167-2738(03)00025-0</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0167-2738 |
| ispartof | Solid state ionics, 2003-03, Vol.159 (1), p.111-119 |
| issn | 0167-2738 1872-7689 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | Composite polymer electrolyte Electrochemical stability Inorganic filler Ionic conductivity Lithium battery |
| title | Electrochemical stability and conductivity enhancement of composite polymer electrolytes |
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