Natural rubber-based nanocomposites by latex compounding with layered silicates

Natural rubber (NR) based nanocomposites with 10 wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Polymer (Guilford) 2003-08, Vol.44 (17), p.4921-4927
Hauptverfasser: Varghese, Siby, Karger-Kocsis, J.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 4927
container_issue 17
container_start_page 4921
container_title Polymer (Guilford)
container_volume 44
creator Varghese, Siby
Karger-Kocsis, J.
description Natural rubber (NR) based nanocomposites with 10 wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix.
doi_str_mv 10.1016/S0032-3861(03)00480-4
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_27919170</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0032386103004804</els_id><sourcerecordid>27919170</sourcerecordid><originalsourceid>FETCH-LOGICAL-c405t-71c0e6e58302141e4206ac9a4f2c97c722a812d2e7e938603987c53e9489ea903</originalsourceid><addsrcrecordid>eNqFkElLxEAQhRtRcBz9CUIuih6i1UuWPokMbjA4B_XcdDoVbckkY1eizr83s6BHTwWP79Wreowdc7jgwNPLJwApYpmn_AzkOYDKIVY7bMTzTMZCaL7LRr_IPjsgegcAkQg1YrNH2_XB1lHoiwJDXFjCMmps07p2vmjJd0hRsYxq2-F3tNb6pvTNa_Tlu7dBXmIYDORr7waEDtleZWvCo-0cs5fbm-fJfTyd3T1MrqexU5B0ccYdYIpJLkFwxVEJSK3TVlXC6cxlQtici1Jghnq4GqTOM5dI1CrXaDXIMTvd7F2E9qNH6szck8O6tg22PRmRaa55tgKTDehCSxSwMovg5zYsDQezqs-s6zOrbgxIs67PqMF3sg2w5GxdBds4T39mpaXmMhm4qw2Hw7efHoMh57FxWPqArjNl6_9J-gGgsoPA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>27919170</pqid></control><display><type>article</type><title>Natural rubber-based nanocomposites by latex compounding with layered silicates</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Varghese, Siby ; Karger-Kocsis, J.</creator><creatorcontrib>Varghese, Siby ; Karger-Kocsis, J.</creatorcontrib><description>Natural rubber (NR) based nanocomposites with 10 wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/S0032-3861(03)00480-4</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; Layered silicates ; Nanocomposites ; Natural rubber latex ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Polymer (Guilford), 2003-08, Vol.44 (17), p.4921-4927</ispartof><rights>2003 Elsevier Science Ltd</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c405t-71c0e6e58302141e4206ac9a4f2c97c722a812d2e7e938603987c53e9489ea903</citedby><cites>FETCH-LOGICAL-c405t-71c0e6e58302141e4206ac9a4f2c97c722a812d2e7e938603987c53e9489ea903</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0032386103004804$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=14939135$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Varghese, Siby</creatorcontrib><creatorcontrib>Karger-Kocsis, J.</creatorcontrib><title>Natural rubber-based nanocomposites by latex compounding with layered silicates</title><title>Polymer (Guilford)</title><description>Natural rubber (NR) based nanocomposites with 10 wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Layered silicates</subject><subject>Nanocomposites</subject><subject>Natural rubber latex</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkElLxEAQhRtRcBz9CUIuih6i1UuWPokMbjA4B_XcdDoVbckkY1eizr83s6BHTwWP79Wreowdc7jgwNPLJwApYpmn_AzkOYDKIVY7bMTzTMZCaL7LRr_IPjsgegcAkQg1YrNH2_XB1lHoiwJDXFjCMmps07p2vmjJd0hRsYxq2-F3tNb6pvTNa_Tlu7dBXmIYDORr7waEDtleZWvCo-0cs5fbm-fJfTyd3T1MrqexU5B0ccYdYIpJLkFwxVEJSK3TVlXC6cxlQtici1Jghnq4GqTOM5dI1CrXaDXIMTvd7F2E9qNH6szck8O6tg22PRmRaa55tgKTDehCSxSwMovg5zYsDQezqs-s6zOrbgxIs67PqMF3sg2w5GxdBds4T39mpaXmMhm4qw2Hw7efHoMh57FxWPqArjNl6_9J-gGgsoPA</recordid><startdate>20030801</startdate><enddate>20030801</enddate><creator>Varghese, Siby</creator><creator>Karger-Kocsis, J.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20030801</creationdate><title>Natural rubber-based nanocomposites by latex compounding with layered silicates</title><author>Varghese, Siby ; Karger-Kocsis, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-71c0e6e58302141e4206ac9a4f2c97c722a812d2e7e938603987c53e9489ea903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Layered silicates</topic><topic>Nanocomposites</topic><topic>Natural rubber latex</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Varghese, Siby</creatorcontrib><creatorcontrib>Karger-Kocsis, J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Varghese, Siby</au><au>Karger-Kocsis, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Natural rubber-based nanocomposites by latex compounding with layered silicates</atitle><jtitle>Polymer (Guilford)</jtitle><date>2003-08-01</date><risdate>2003</risdate><volume>44</volume><issue>17</issue><spage>4921</spage><epage>4927</epage><pages>4921-4927</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Natural rubber (NR) based nanocomposites with 10 wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0032-3861(03)00480-4</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0032-3861
ispartof Polymer (Guilford), 2003-08, Vol.44 (17), p.4921-4927
issn 0032-3861
1873-2291
language eng
recordid cdi_proquest_miscellaneous_27919170
source Elsevier ScienceDirect Journals Complete
subjects Applied sciences
Composites
Exact sciences and technology
Forms of application and semi-finished materials
Layered silicates
Nanocomposites
Natural rubber latex
Polymer industry, paints, wood
Technology of polymers
title Natural rubber-based nanocomposites by latex compounding with layered silicates
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-06T10%3A45%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Natural%20rubber-based%20nanocomposites%20by%20latex%20compounding%20with%20layered%20silicates&rft.jtitle=Polymer%20(Guilford)&rft.au=Varghese,%20Siby&rft.date=2003-08-01&rft.volume=44&rft.issue=17&rft.spage=4921&rft.epage=4927&rft.pages=4921-4927&rft.issn=0032-3861&rft.eissn=1873-2291&rft.coden=POLMAG&rft_id=info:doi/10.1016/S0032-3861(03)00480-4&rft_dat=%3Cproquest_cross%3E27919170%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=27919170&rft_id=info:pmid/&rft_els_id=S0032386103004804&rfr_iscdi=true