Natural rubber-based nanocomposites by latex compounding with layered silicates
Natural rubber (NR) based nanocomposites with 10 wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India...
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Veröffentlicht in: | Polymer (Guilford) 2003-08, Vol.44 (17), p.4921-4927 |
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creator | Varghese, Siby Karger-Kocsis, J. |
description | Natural rubber (NR) based nanocomposites with 10
wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix. |
doi_str_mv | 10.1016/S0032-3861(03)00480-4 |
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wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Layered silicates</subject><subject>Nanocomposites</subject><subject>Natural rubber latex</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkElLxEAQhRtRcBz9CUIuih6i1UuWPokMbjA4B_XcdDoVbckkY1eizr83s6BHTwWP79Wreowdc7jgwNPLJwApYpmn_AzkOYDKIVY7bMTzTMZCaL7LRr_IPjsgegcAkQg1YrNH2_XB1lHoiwJDXFjCMmps07p2vmjJd0hRsYxq2-F3tNb6pvTNa_Tlu7dBXmIYDORr7waEDtleZWvCo-0cs5fbm-fJfTyd3T1MrqexU5B0ccYdYIpJLkFwxVEJSK3TVlXC6cxlQtici1Jghnq4GqTOM5dI1CrXaDXIMTvd7F2E9qNH6szck8O6tg22PRmRaa55tgKTDehCSxSwMovg5zYsDQezqs-s6zOrbgxIs67PqMF3sg2w5GxdBds4T39mpaXmMhm4qw2Hw7efHoMh57FxWPqArjNl6_9J-gGgsoPA</recordid><startdate>20030801</startdate><enddate>20030801</enddate><creator>Varghese, Siby</creator><creator>Karger-Kocsis, J.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20030801</creationdate><title>Natural rubber-based nanocomposites by latex compounding with layered silicates</title><author>Varghese, Siby ; Karger-Kocsis, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-71c0e6e58302141e4206ac9a4f2c97c722a812d2e7e938603987c53e9489ea903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Layered silicates</topic><topic>Nanocomposites</topic><topic>Natural rubber latex</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Varghese, Siby</creatorcontrib><creatorcontrib>Karger-Kocsis, J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Varghese, Siby</au><au>Karger-Kocsis, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Natural rubber-based nanocomposites by latex compounding with layered silicates</atitle><jtitle>Polymer (Guilford)</jtitle><date>2003-08-01</date><risdate>2003</risdate><volume>44</volume><issue>17</issue><spage>4921</spage><epage>4927</epage><pages>4921-4927</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Natural rubber (NR) based nanocomposites with 10
wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0032-3861(03)00480-4</doi><tpages>7</tpages></addata></record> |
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subjects | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Layered silicates Nanocomposites Natural rubber latex Polymer industry, paints, wood Technology of polymers |
title | Natural rubber-based nanocomposites by latex compounding with layered silicates |
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