Layered Co–O Cluster Applied to Photocatalytic CO2 Reduction

Layered Co–O Cluster Applied to Photocatalytic CO2 Reduction

In the field of recycling CO2, the photocatalytic CO2 reduction reaction (CO2RR) is a typical example, and researchers have designed a variety of photocatalysts to improve the conversion rate of CO2 over the years. In this paper, two metal–oxygen clusters are designed and formulated as [Co3Zn­(OH)6(...

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Veröffentlicht in:Inorganic chemistry 2023-04, Vol.62 (13), p.5200-5206
Hauptverfasser: Xiang, Xin-Ying, Zhou, Jiu-Lin, Wang, Qin, Zhu, Yin-Hua, Zhang, Zhen-Tao, Ye, Tian-Cheng, Wang, Ji-Lei, Chen, Qiao-Ling, Xu, Yan
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container_end_page 5206
container_issue 13
container_start_page 5200
container_title Inorganic chemistry
container_volume 62
creator Xiang, Xin-Ying
Zhou, Jiu-Lin
Wang, Qin
Zhu, Yin-Hua
Zhang, Zhen-Tao
Ye, Tian-Cheng
Wang, Ji-Lei
Chen, Qiao-Ling
Xu, Yan
description In the field of recycling CO2, the photocatalytic CO2 reduction reaction (CO2RR) is a typical example, and researchers have designed a variety of photocatalysts to improve the conversion rate of CO2 over the years. In this paper, two metal–oxygen clusters are designed and formulated as [Co3Zn­(OH)6(SO4)]·4H2O (1) and [Ni3Zn­(OH)6(SO4)]·4H2O (2). As for compound 1, the main structure is composed of {CoO6} octahedra connected by edge-sharing to form a two-dimensional layer, on which {ZnO4} and {SO4} tetrahedra are supported. More interestingly, compound 1 has outstanding photocatalytic activity, which is mainly attributed to the open-framework structure and the cobalt ions as active sites. Upon catalysis for eight hours, its maximum CO generation rate is 9982.13 μmol g–1 h–1, with a selectivity of 81.8%. Additionally, compound 1 takes on weak antiferromagnetic coupling due to Co­(II) ions.
doi_str_mv 10.1021/acs.inorgchem.3c00184
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