A Janus Separator based on Cation Exchange Resin and Fe Nanoparticles‐decorated Single‐wall Carbon Nanotubes with Triply Synergistic Effects for High‐areal Capacity Zn−I2 Batteries
Zn−I2 batteries stand out in the family of aqueous Zn‐metal batteries (AZMBs) due to their low‐cost and immanent safety. However, Zn dendrite growth, polyiodide shuttle effect and sluggish I2 redox kinetics result in dramatically capacity decay of Zn−I2 batteries. Herein, a Janus separator composed...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2023-05, Vol.62 (22), p.e202300418-n/a |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 22 |
| container_start_page | e202300418 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 62 |
| creator | Kang, Yuanhong Chen, Guanhong Hua, Haiming Zhang, Minghao Yang, Jin Lin, Pengxiang Yang, Huiya Lv, Zeheng Wu, Qilong Zhao, Jinbao Yang, Yang |
| description | Zn−I2 batteries stand out in the family of aqueous Zn‐metal batteries (AZMBs) due to their low‐cost and immanent safety. However, Zn dendrite growth, polyiodide shuttle effect and sluggish I2 redox kinetics result in dramatically capacity decay of Zn−I2 batteries. Herein, a Janus separator composed of functional layers on anode/cathode sides is designed to resolve these issues simultaneously. The cathode layer of Fe nanoparticles‐decorated single‐wall carbon nanotubes can effectively anchor polyiodide and catalyze the redox kinetics of iodine species, while the anode layer of cation exchange resin rich in −SO3− groups is beneficial to attract Zn2+ ions and repel detrimental SO42−/polyiodide, improving the stability of cathode/anode interfaces synergistically. Consequently, the Janus separator endows outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 batteries with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2.
A Janus separator based on cation exchange resin and Fe nanoparticles‐decorated single‐wall carbon nanotubes with triple synergistic effects is exploited to suppress Zn dendrites growth, mitigate polyiodide shuttle effect and facilitate redox kinetics of iodine species. This is reflected in the outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 battery with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2. |
| doi_str_mv | 10.1002/anie.202300418 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_miscellaneous_2789234395</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2812896625</sourcerecordid><originalsourceid>FETCH-LOGICAL-p3068-c833038dd0b1438363d3dca937c8fb20f6749af2d16c1eb1520f4e08461569e13</originalsourceid><addsrcrecordid>eNpdkc9u1DAQhyMEEqVw5WyJC5e0_pNNnOOy2tJFVSt1y4WLNXEmu65cJ9iOltw4cqx4Hp6mT4KjVj30NPbom0-j-WXZR0ZPGKX8FJzBE065oLRg8lV2xBac5aKqxOv0LoTIK7lgb7N3IdwmXkpaHmX_luQbuDGQLQ7gIfaeNBCwJb0jK4gmlfUvvQe3Q3KNwTgCriVnSC7B9WkiGm0xPPy-b1H3aT5Nbo3bWUytA1ibJL5JkhmPY4OBHEzckxtvBjuR7eTQ70xIFrLuOtQxkC6tcG52-yQAjzAbBtAmTuSHe_jzd8PJF4gRvcHwPnvTgQ344akeZ9_P1jer8_zi6utmtbzIB0FLmWspBBWybWmTziBFKVrRaqhFpWXXcNqVVVFDx1tWaoZNOhvtCqSyKNmirJGJ4-zzo3fw_c8RQ1R3Jmi0Fhz2Y1C8kjUXhagXCf30Ar3tR-_SdopLxmVdlnym6kfqYCxOavDmDvykGFVzkmpOUj0nqZaXm_XzT_wHZmOZ7Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2812896625</pqid></control><display><type>article</type><title>A Janus Separator based on Cation Exchange Resin and Fe Nanoparticles‐decorated Single‐wall Carbon Nanotubes with Triply Synergistic Effects for High‐areal Capacity Zn−I2 Batteries</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Kang, Yuanhong ; Chen, Guanhong ; Hua, Haiming ; Zhang, Minghao ; Yang, Jin ; Lin, Pengxiang ; Yang, Huiya ; Lv, Zeheng ; Wu, Qilong ; Zhao, Jinbao ; Yang, Yang</creator><creatorcontrib>Kang, Yuanhong ; Chen, Guanhong ; Hua, Haiming ; Zhang, Minghao ; Yang, Jin ; Lin, Pengxiang ; Yang, Huiya ; Lv, Zeheng ; Wu, Qilong ; Zhao, Jinbao ; Yang, Yang</creatorcontrib><description>Zn−I2 batteries stand out in the family of aqueous Zn‐metal batteries (AZMBs) due to their low‐cost and immanent safety. However, Zn dendrite growth, polyiodide shuttle effect and sluggish I2 redox kinetics result in dramatically capacity decay of Zn−I2 batteries. Herein, a Janus separator composed of functional layers on anode/cathode sides is designed to resolve these issues simultaneously. The cathode layer of Fe nanoparticles‐decorated single‐wall carbon nanotubes can effectively anchor polyiodide and catalyze the redox kinetics of iodine species, while the anode layer of cation exchange resin rich in −SO3− groups is beneficial to attract Zn2+ ions and repel detrimental SO42−/polyiodide, improving the stability of cathode/anode interfaces synergistically. Consequently, the Janus separator endows outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 batteries with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2.
A Janus separator based on cation exchange resin and Fe nanoparticles‐decorated single‐wall carbon nanotubes with triple synergistic effects is exploited to suppress Zn dendrites growth, mitigate polyiodide shuttle effect and facilitate redox kinetics of iodine species. This is reflected in the outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 battery with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202300418</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Batteries ; Carbon ; Carbon nanotubes ; Cathodes ; Cation exchange ; Cation Exchange Resin ; Cation exchanging ; Cationic polymerization ; Fe Nanoparticles-Decorated Single-Wall Carbon Nanotube ; Interface stability ; Iodine ; Iron ; Janus Separator ; Kinetics ; Life span ; Nanoparticles ; Nanotechnology ; Nanotubes ; Reaction kinetics ; Redox Kinetics ; Resins ; Separators ; Sulfur trioxide ; Synergistic effect ; Zinc ; Zinc-Iodine Batteries</subject><ispartof>Angewandte Chemie International Edition, 2023-05, Vol.62 (22), p.e202300418-n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-2753-7508</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202300418$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202300418$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Kang, Yuanhong</creatorcontrib><creatorcontrib>Chen, Guanhong</creatorcontrib><creatorcontrib>Hua, Haiming</creatorcontrib><creatorcontrib>Zhang, Minghao</creatorcontrib><creatorcontrib>Yang, Jin</creatorcontrib><creatorcontrib>Lin, Pengxiang</creatorcontrib><creatorcontrib>Yang, Huiya</creatorcontrib><creatorcontrib>Lv, Zeheng</creatorcontrib><creatorcontrib>Wu, Qilong</creatorcontrib><creatorcontrib>Zhao, Jinbao</creatorcontrib><creatorcontrib>Yang, Yang</creatorcontrib><title>A Janus Separator based on Cation Exchange Resin and Fe Nanoparticles‐decorated Single‐wall Carbon Nanotubes with Triply Synergistic Effects for High‐areal Capacity Zn−I2 Batteries</title><title>Angewandte Chemie International Edition</title><description>Zn−I2 batteries stand out in the family of aqueous Zn‐metal batteries (AZMBs) due to their low‐cost and immanent safety. However, Zn dendrite growth, polyiodide shuttle effect and sluggish I2 redox kinetics result in dramatically capacity decay of Zn−I2 batteries. Herein, a Janus separator composed of functional layers on anode/cathode sides is designed to resolve these issues simultaneously. The cathode layer of Fe nanoparticles‐decorated single‐wall carbon nanotubes can effectively anchor polyiodide and catalyze the redox kinetics of iodine species, while the anode layer of cation exchange resin rich in −SO3− groups is beneficial to attract Zn2+ ions and repel detrimental SO42−/polyiodide, improving the stability of cathode/anode interfaces synergistically. Consequently, the Janus separator endows outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 batteries with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2.
A Janus separator based on cation exchange resin and Fe nanoparticles‐decorated single‐wall carbon nanotubes with triple synergistic effects is exploited to suppress Zn dendrites growth, mitigate polyiodide shuttle effect and facilitate redox kinetics of iodine species. This is reflected in the outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 battery with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2.</description><subject>Batteries</subject><subject>Carbon</subject><subject>Carbon nanotubes</subject><subject>Cathodes</subject><subject>Cation exchange</subject><subject>Cation Exchange Resin</subject><subject>Cation exchanging</subject><subject>Cationic polymerization</subject><subject>Fe Nanoparticles-Decorated Single-Wall Carbon Nanotube</subject><subject>Interface stability</subject><subject>Iodine</subject><subject>Iron</subject><subject>Janus Separator</subject><subject>Kinetics</subject><subject>Life span</subject><subject>Nanoparticles</subject><subject>Nanotechnology</subject><subject>Nanotubes</subject><subject>Reaction kinetics</subject><subject>Redox Kinetics</subject><subject>Resins</subject><subject>Separators</subject><subject>Sulfur trioxide</subject><subject>Synergistic effect</subject><subject>Zinc</subject><subject>Zinc-Iodine Batteries</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkc9u1DAQhyMEEqVw5WyJC5e0_pNNnOOy2tJFVSt1y4WLNXEmu65cJ9iOltw4cqx4Hp6mT4KjVj30NPbom0-j-WXZR0ZPGKX8FJzBE065oLRg8lV2xBac5aKqxOv0LoTIK7lgb7N3IdwmXkpaHmX_luQbuDGQLQ7gIfaeNBCwJb0jK4gmlfUvvQe3Q3KNwTgCriVnSC7B9WkiGm0xPPy-b1H3aT5Nbo3bWUytA1ibJL5JkhmPY4OBHEzckxtvBjuR7eTQ70xIFrLuOtQxkC6tcG52-yQAjzAbBtAmTuSHe_jzd8PJF4gRvcHwPnvTgQ344akeZ9_P1jer8_zi6utmtbzIB0FLmWspBBWybWmTziBFKVrRaqhFpWXXcNqVVVFDx1tWaoZNOhvtCqSyKNmirJGJ4-zzo3fw_c8RQ1R3Jmi0Fhz2Y1C8kjUXhagXCf30Ar3tR-_SdopLxmVdlnym6kfqYCxOavDmDvykGFVzkmpOUj0nqZaXm_XzT_wHZmOZ7Q</recordid><startdate>20230522</startdate><enddate>20230522</enddate><creator>Kang, Yuanhong</creator><creator>Chen, Guanhong</creator><creator>Hua, Haiming</creator><creator>Zhang, Minghao</creator><creator>Yang, Jin</creator><creator>Lin, Pengxiang</creator><creator>Yang, Huiya</creator><creator>Lv, Zeheng</creator><creator>Wu, Qilong</creator><creator>Zhao, Jinbao</creator><creator>Yang, Yang</creator><general>Wiley Subscription Services, Inc</general><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-2753-7508</orcidid></search><sort><creationdate>20230522</creationdate><title>A Janus Separator based on Cation Exchange Resin and Fe Nanoparticles‐decorated Single‐wall Carbon Nanotubes with Triply Synergistic Effects for High‐areal Capacity Zn−I2 Batteries</title><author>Kang, Yuanhong ; Chen, Guanhong ; Hua, Haiming ; Zhang, Minghao ; Yang, Jin ; Lin, Pengxiang ; Yang, Huiya ; Lv, Zeheng ; Wu, Qilong ; Zhao, Jinbao ; Yang, Yang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p3068-c833038dd0b1438363d3dca937c8fb20f6749af2d16c1eb1520f4e08461569e13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Batteries</topic><topic>Carbon</topic><topic>Carbon nanotubes</topic><topic>Cathodes</topic><topic>Cation exchange</topic><topic>Cation Exchange Resin</topic><topic>Cation exchanging</topic><topic>Cationic polymerization</topic><topic>Fe Nanoparticles-Decorated Single-Wall Carbon Nanotube</topic><topic>Interface stability</topic><topic>Iodine</topic><topic>Iron</topic><topic>Janus Separator</topic><topic>Kinetics</topic><topic>Life span</topic><topic>Nanoparticles</topic><topic>Nanotechnology</topic><topic>Nanotubes</topic><topic>Reaction kinetics</topic><topic>Redox Kinetics</topic><topic>Resins</topic><topic>Separators</topic><topic>Sulfur trioxide</topic><topic>Synergistic effect</topic><topic>Zinc</topic><topic>Zinc-Iodine Batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kang, Yuanhong</creatorcontrib><creatorcontrib>Chen, Guanhong</creatorcontrib><creatorcontrib>Hua, Haiming</creatorcontrib><creatorcontrib>Zhang, Minghao</creatorcontrib><creatorcontrib>Yang, Jin</creatorcontrib><creatorcontrib>Lin, Pengxiang</creatorcontrib><creatorcontrib>Yang, Huiya</creatorcontrib><creatorcontrib>Lv, Zeheng</creatorcontrib><creatorcontrib>Wu, Qilong</creatorcontrib><creatorcontrib>Zhao, Jinbao</creatorcontrib><creatorcontrib>Yang, Yang</creatorcontrib><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kang, Yuanhong</au><au>Chen, Guanhong</au><au>Hua, Haiming</au><au>Zhang, Minghao</au><au>Yang, Jin</au><au>Lin, Pengxiang</au><au>Yang, Huiya</au><au>Lv, Zeheng</au><au>Wu, Qilong</au><au>Zhao, Jinbao</au><au>Yang, Yang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Janus Separator based on Cation Exchange Resin and Fe Nanoparticles‐decorated Single‐wall Carbon Nanotubes with Triply Synergistic Effects for High‐areal Capacity Zn−I2 Batteries</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2023-05-22</date><risdate>2023</risdate><volume>62</volume><issue>22</issue><spage>e202300418</spage><epage>n/a</epage><pages>e202300418-n/a</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Zn−I2 batteries stand out in the family of aqueous Zn‐metal batteries (AZMBs) due to their low‐cost and immanent safety. However, Zn dendrite growth, polyiodide shuttle effect and sluggish I2 redox kinetics result in dramatically capacity decay of Zn−I2 batteries. Herein, a Janus separator composed of functional layers on anode/cathode sides is designed to resolve these issues simultaneously. The cathode layer of Fe nanoparticles‐decorated single‐wall carbon nanotubes can effectively anchor polyiodide and catalyze the redox kinetics of iodine species, while the anode layer of cation exchange resin rich in −SO3− groups is beneficial to attract Zn2+ ions and repel detrimental SO42−/polyiodide, improving the stability of cathode/anode interfaces synergistically. Consequently, the Janus separator endows outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 batteries with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2.
A Janus separator based on cation exchange resin and Fe nanoparticles‐decorated single‐wall carbon nanotubes with triple synergistic effects is exploited to suppress Zn dendrites growth, mitigate polyiodide shuttle effect and facilitate redox kinetics of iodine species. This is reflected in the outstanding cycling stability of symmetrical cells and high‐areal‐capacity Zn−I2 battery with a lifespan over 2500 h and a high‐areal capacity of 3.6 mAh cm−2.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/anie.202300418</doi><tpages>10</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-2753-7508</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2023-05, Vol.62 (22), p.e202300418-n/a |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2789234395 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Batteries Carbon Carbon nanotubes Cathodes Cation exchange Cation Exchange Resin Cation exchanging Cationic polymerization Fe Nanoparticles-Decorated Single-Wall Carbon Nanotube Interface stability Iodine Iron Janus Separator Kinetics Life span Nanoparticles Nanotechnology Nanotubes Reaction kinetics Redox Kinetics Resins Separators Sulfur trioxide Synergistic effect Zinc Zinc-Iodine Batteries |
| title | A Janus Separator based on Cation Exchange Resin and Fe Nanoparticles‐decorated Single‐wall Carbon Nanotubes with Triply Synergistic Effects for High‐areal Capacity Zn−I2 Batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T13%3A16%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20Janus%20Separator%20based%20on%20Cation%20Exchange%20Resin%20and%20Fe%20Nanoparticles%E2%80%90decorated%20Single%E2%80%90wall%20Carbon%20Nanotubes%20with%20Triply%20Synergistic%20Effects%20for%20High%E2%80%90areal%20Capacity%20Zn%E2%88%92I2%20Batteries&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Kang,%20Yuanhong&rft.date=2023-05-22&rft.volume=62&rft.issue=22&rft.spage=e202300418&rft.epage=n/a&rft.pages=e202300418-n/a&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.202300418&rft_dat=%3Cproquest_wiley%3E2812896625%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2812896625&rft_id=info:pmid/&rfr_iscdi=true |