Nucleation ability of multiwall carbon nanotubes in polypropylene composites
The nonisothermal crystallization of multiwall carbon nanotube (MWNT)/isotactic polypropylene (iPP) nanocomposites was investigated. The results derived from the differential scanning calorimetry curves (onset temperature, melting point, supercooling, peak temperature, half‐time of crystallization,...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2003-03, Vol.41 (5), p.520-527 |
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| container_end_page | 527 |
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| container_issue | 5 |
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| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 41 |
| creator | Assouline, E. Lustiger, A. Barber, A. H. Cooper, C. A. Klein, E. Wachtel, E. Wagner, H. D. |
| description | The nonisothermal crystallization of multiwall carbon nanotube (MWNT)/isotactic polypropylene (iPP) nanocomposites was investigated. The results derived from the differential scanning calorimetry curves (onset temperature, melting point, supercooling, peak temperature, half‐time of crystallization, and enthalpy of crystallization) were compared with those of neat iPP. The data were also processed according to Ozawa's theory and Dobreva's approach. These results and X‐ray diffraction data showed that the MWNTs acted as α‐nucleating agents in iPP. Accordingly, MWNT/iPP was significantly different from neat iPP: A fibrillar morphology was observed instead of the usual spherulites. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 520–527, 2003 |
| doi_str_mv | 10.1002/polb.10394 |
| format | Article |
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H. ; Cooper, C. A. ; Klein, E. ; Wachtel, E. ; Wagner, H. D.</creator><creatorcontrib>Assouline, E. ; Lustiger, A. ; Barber, A. H. ; Cooper, C. A. ; Klein, E. ; Wachtel, E. ; Wagner, H. D.</creatorcontrib><description>The nonisothermal crystallization of multiwall carbon nanotube (MWNT)/isotactic polypropylene (iPP) nanocomposites was investigated. The results derived from the differential scanning calorimetry curves (onset temperature, melting point, supercooling, peak temperature, half‐time of crystallization, and enthalpy of crystallization) were compared with those of neat iPP. The data were also processed according to Ozawa's theory and Dobreva's approach. These results and X‐ray diffraction data showed that the MWNTs acted as α‐nucleating agents in iPP. Accordingly, MWNT/iPP was significantly different from neat iPP: A fibrillar morphology was observed instead of the usual spherulites. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 520–527, 2003</description><identifier>ISSN: 0887-6266</identifier><identifier>EISSN: 1099-0488</identifier><identifier>DOI: 10.1002/polb.10394</identifier><identifier>CODEN: JPLPAY</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; carbon nanotubes ; Composites ; crystallization ; Exact sciences and technology ; Forms of application and semi-finished materials ; morphology ; nanocomposites ; poly(propylene) (PP) ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Journal of polymer science. 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H.</creatorcontrib><creatorcontrib>Cooper, C. A.</creatorcontrib><creatorcontrib>Klein, E.</creatorcontrib><creatorcontrib>Wachtel, E.</creatorcontrib><creatorcontrib>Wagner, H. D.</creatorcontrib><title>Nucleation ability of multiwall carbon nanotubes in polypropylene composites</title><title>Journal of polymer science. Part B, Polymer physics</title><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><description>The nonisothermal crystallization of multiwall carbon nanotube (MWNT)/isotactic polypropylene (iPP) nanocomposites was investigated. The results derived from the differential scanning calorimetry curves (onset temperature, melting point, supercooling, peak temperature, half‐time of crystallization, and enthalpy of crystallization) were compared with those of neat iPP. The data were also processed according to Ozawa's theory and Dobreva's approach. These results and X‐ray diffraction data showed that the MWNTs acted as α‐nucleating agents in iPP. Accordingly, MWNT/iPP was significantly different from neat iPP: A fibrillar morphology was observed instead of the usual spherulites. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 520–527, 2003</description><subject>Applied sciences</subject><subject>carbon nanotubes</subject><subject>Composites</subject><subject>crystallization</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>morphology</subject><subject>nanocomposites</subject><subject>poly(propylene) (PP)</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNp9kEtPwzAQhC0EEqVw4RfkAgekgONH7ByhogVRtRxAHC3bdSSDEwc7Ucm_JyU8bpx2pflmdjUAnGbwMoMQXTXeqWHDBdkDkwwWRQoJ5_tgAjlnaY7y_BAcxfgK4aDRYgKWq047I1vr60Qq62zbJ75Mqs61diudS7QMatBqWfu2UyYmtk6GK30TfNM7U5tE-6rx0bYmHoODUrpoTr7nFDzPb59md-lyvbifXS9TTXBOUkUoLjk2WDHDIc8YRQXDGwYzjKnkivBCkoKWmCvNidpIxgkjJTKIEUS4xFNwPuYOT7x3JraislEb52RtfBcFYpzhHMEBvBhBHXyMwZSiCbaSoRcZFLvCxK4w8VXYAJ99p8qopSuDrLWNfw5Cc5YRPnDZyG2tM_0_ieJxvbz5yU5Hj42t-fj1yPAmcoYZFS-rhWDzGUQPiIoF_gRr4onL</recordid><startdate>20030301</startdate><enddate>20030301</enddate><creator>Assouline, E.</creator><creator>Lustiger, A.</creator><creator>Barber, A. 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B Polym. Phys</addtitle><date>2003-03-01</date><risdate>2003</risdate><volume>41</volume><issue>5</issue><spage>520</spage><epage>527</epage><pages>520-527</pages><issn>0887-6266</issn><eissn>1099-0488</eissn><coden>JPLPAY</coden><abstract>The nonisothermal crystallization of multiwall carbon nanotube (MWNT)/isotactic polypropylene (iPP) nanocomposites was investigated. The results derived from the differential scanning calorimetry curves (onset temperature, melting point, supercooling, peak temperature, half‐time of crystallization, and enthalpy of crystallization) were compared with those of neat iPP. The data were also processed according to Ozawa's theory and Dobreva's approach. These results and X‐ray diffraction data showed that the MWNTs acted as α‐nucleating agents in iPP. Accordingly, MWNT/iPP was significantly different from neat iPP: A fibrillar morphology was observed instead of the usual spherulites. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 520–527, 2003</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/polb.10394</doi><tpages>8</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences carbon nanotubes Composites crystallization Exact sciences and technology Forms of application and semi-finished materials morphology nanocomposites poly(propylene) (PP) Polymer industry, paints, wood Technology of polymers |
| title | Nucleation ability of multiwall carbon nanotubes in polypropylene composites |
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