Effect of temperature on excess molar volumes and viscosities of binary mixtures of ethylenediamine and water
Molar excess volumes ( V E) and viscosities have been evaluated for binary mixtures of ethylenediamine and water in the temperature range from 303.15 to 318.15 K at an interval of 5 K. Excess molar volumes V E have been computed from density while excess Gibbs free energy of activation Δ G ∗E is cal...
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| Veröffentlicht in: | Fluid phase equilibria 2003-04, Vol.205 (2), p.267-274 |
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| container_title | Fluid phase equilibria |
| container_volume | 205 |
| creator | Kapadi, U.R. Hundiwale, D.G. Patil, N.B. Lande, M.K. |
| description | Molar excess volumes (
V
E) and viscosities have been evaluated for binary mixtures of ethylenediamine and water in the temperature range from 303.15 to 318.15
K at an interval of 5
K. Excess molar volumes
V
E have been computed from density while excess Gibbs free energy of activation Δ
G
∗E is calculated from viscosity deviation Δ
η. The results were applied to Redlich–Kister equation. It is observed that all mixtures show negative values of
V
E obviously due to increased interactions between amino and hydroxyl groups of the components. |
| doi_str_mv | 10.1016/S0378-3812(02)00293-5 |
| format | Article |
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V
E) and viscosities have been evaluated for binary mixtures of ethylenediamine and water in the temperature range from 303.15 to 318.15
K at an interval of 5
K. Excess molar volumes
V
E have been computed from density while excess Gibbs free energy of activation Δ
G
∗E is calculated from viscosity deviation Δ
η. The results were applied to Redlich–Kister equation. It is observed that all mixtures show negative values of
V
E obviously due to increased interactions between amino and hydroxyl groups of the components.</description><identifier>ISSN: 0378-3812</identifier><identifier>EISSN: 1879-0224</identifier><identifier>DOI: 10.1016/S0378-3812(02)00293-5</identifier><identifier>CODEN: FPEQDT</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Binary mixtures ; Chemical thermodynamics ; Chemistry ; Density ; Ethylenediamine ; Exact sciences and technology ; Excess parameter ; General and physical chemistry ; Mixtures ; Molecular interaction viscosities ; Redlich–Kister equation ; Thermodynamic properties</subject><ispartof>Fluid phase equilibria, 2003-04, Vol.205 (2), p.267-274</ispartof><rights>2002 Elsevier Science B.V.</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c471t-f4b563e5b102f7774da4afd0a5eda9ddd432c43f67d2e5cd2d21e70eb37904a03</citedby><cites>FETCH-LOGICAL-c471t-f4b563e5b102f7774da4afd0a5eda9ddd432c43f67d2e5cd2d21e70eb37904a03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0378381202002935$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14735879$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kapadi, U.R.</creatorcontrib><creatorcontrib>Hundiwale, D.G.</creatorcontrib><creatorcontrib>Patil, N.B.</creatorcontrib><creatorcontrib>Lande, M.K.</creatorcontrib><title>Effect of temperature on excess molar volumes and viscosities of binary mixtures of ethylenediamine and water</title><title>Fluid phase equilibria</title><description>Molar excess volumes (
V
E) and viscosities have been evaluated for binary mixtures of ethylenediamine and water in the temperature range from 303.15 to 318.15
K at an interval of 5
K. Excess molar volumes
V
E have been computed from density while excess Gibbs free energy of activation Δ
G
∗E is calculated from viscosity deviation Δ
η. The results were applied to Redlich–Kister equation. It is observed that all mixtures show negative values of
V
E obviously due to increased interactions between amino and hydroxyl groups of the components.</description><subject>Binary mixtures</subject><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Density</subject><subject>Ethylenediamine</subject><subject>Exact sciences and technology</subject><subject>Excess parameter</subject><subject>General and physical chemistry</subject><subject>Mixtures</subject><subject>Molecular interaction viscosities</subject><subject>Redlich–Kister equation</subject><subject>Thermodynamic properties</subject><issn>0378-3812</issn><issn>1879-0224</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkE1rGzEQhkVpoK7Tn1DQpSE9bDL6suxTKcZNAoYckp6FLI2oyu7KkdaO_e8jf5AeCwKh4Xk1Mw8hXxncMGCT2ycQetqIKePXwL8D8Jlo1AcyYlM9a4Bz-ZGM3pFP5HMpfwGAqQkfkW4RArqBpkAH7NaY7bDJSFNPceewFNql1ma6Te2mw0Jt7-k2FpdKHGJ919gq9jbvaRd3h-SxhMOffYs9-mi72OMx9WoHzJfkIti24JfzPSa_fy2e5_fN8vHuYf5z2Tip2dAEuVITgWrFgAettfRW2uDBKvR25r2XgjspwkR7jsp57jlDDbgSegbSghiTq9O_65xeNlgG09WhsW1tj2lTDNdTDQpEBdUJdDmVkjGYdY5d3ccwMAe55ijXHMwZqOcg16ia-3ZuYIuzbci2d7H8C0stVLVfuR8nDuu224jZFBexd1VNrtqNT_E_nd4ATy-Qug</recordid><startdate>20030401</startdate><enddate>20030401</enddate><creator>Kapadi, U.R.</creator><creator>Hundiwale, D.G.</creator><creator>Patil, N.B.</creator><creator>Lande, M.K.</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20030401</creationdate><title>Effect of temperature on excess molar volumes and viscosities of binary mixtures of ethylenediamine and water</title><author>Kapadi, U.R. ; Hundiwale, D.G. ; Patil, N.B. ; Lande, M.K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c471t-f4b563e5b102f7774da4afd0a5eda9ddd432c43f67d2e5cd2d21e70eb37904a03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Binary mixtures</topic><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Density</topic><topic>Ethylenediamine</topic><topic>Exact sciences and technology</topic><topic>Excess parameter</topic><topic>General and physical chemistry</topic><topic>Mixtures</topic><topic>Molecular interaction viscosities</topic><topic>Redlich–Kister equation</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kapadi, U.R.</creatorcontrib><creatorcontrib>Hundiwale, D.G.</creatorcontrib><creatorcontrib>Patil, N.B.</creatorcontrib><creatorcontrib>Lande, M.K.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Fluid phase equilibria</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kapadi, U.R.</au><au>Hundiwale, D.G.</au><au>Patil, N.B.</au><au>Lande, M.K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of temperature on excess molar volumes and viscosities of binary mixtures of ethylenediamine and water</atitle><jtitle>Fluid phase equilibria</jtitle><date>2003-04-01</date><risdate>2003</risdate><volume>205</volume><issue>2</issue><spage>267</spage><epage>274</epage><pages>267-274</pages><issn>0378-3812</issn><eissn>1879-0224</eissn><coden>FPEQDT</coden><abstract>Molar excess volumes (
V
E) and viscosities have been evaluated for binary mixtures of ethylenediamine and water in the temperature range from 303.15 to 318.15
K at an interval of 5
K. Excess molar volumes
V
E have been computed from density while excess Gibbs free energy of activation Δ
G
∗E is calculated from viscosity deviation Δ
η. The results were applied to Redlich–Kister equation. It is observed that all mixtures show negative values of
V
E obviously due to increased interactions between amino and hydroxyl groups of the components.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/S0378-3812(02)00293-5</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0378-3812 |
| ispartof | Fluid phase equilibria, 2003-04, Vol.205 (2), p.267-274 |
| issn | 0378-3812 1879-0224 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Binary mixtures Chemical thermodynamics Chemistry Density Ethylenediamine Exact sciences and technology Excess parameter General and physical chemistry Mixtures Molecular interaction viscosities Redlich–Kister equation Thermodynamic properties |
| title | Effect of temperature on excess molar volumes and viscosities of binary mixtures of ethylenediamine and water |
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