Effect of adsorption of polyoxyethylene laurylether on electrodeposition of Pb-free Sn alloys

Three plating baths (Sn–Cu, Sn–Bi and Sn–Ag–Cu) containing a polyoxyethylene laurylether (POELE) additive were developed as Pb-free solder plating solutions. The addition of POELE afforded a smooth, homogeneous alloy upon deposition. A mechanism for the effect of POELE in the electrodeposition proce...

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Veröffentlicht in:Surface & coatings technology 2003-06, Vol.169, p.128-131
Hauptverfasser: Fukuda, Mitsunobu, Imayoshi, Kohei, Matsumoto, Yasumichi
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creator Fukuda, Mitsunobu
Imayoshi, Kohei
Matsumoto, Yasumichi
description Three plating baths (Sn–Cu, Sn–Bi and Sn–Ag–Cu) containing a polyoxyethylene laurylether (POELE) additive were developed as Pb-free solder plating solutions. The addition of POELE afforded a smooth, homogeneous alloy upon deposition. A mechanism for the effect of POELE in the electrodeposition process is proposed in which POELE adsorbs on deposited Sn surfaces, suppressing subsequent deposition during electrolysis. The POELE remains on the surface of the deposited Sn as the plating layer grows, and is efficiently removed in the final water rinse.
doi_str_mv 10.1016/S0257-8972(03)00191-9
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source ScienceDirect Journals (5 years ago - present)
subjects Bismuth
Copper
Electroplating
Pb-free
Silver
Tin
title Effect of adsorption of polyoxyethylene laurylether on electrodeposition of Pb-free Sn alloys
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