Microbial stability evaluation of cement-based waste forms at different waste to cement ratio

An evaluation of the effect of differences in chromium nitrate to cement ratio on the microbial stability of a chromium nitrate/cement waste form, as reflected in the leaching of chromium, calcium, magnesium and aluminum; was carried out in this study. An increase in the proportion of chromium in th...

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Veröffentlicht in:Journal of hazardous materials 2003-01, Vol.96 (2), p.331-340
Hauptverfasser: Idachaba, Michael A, Nyavor, Kafui, Egiebor, Nosa O
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Nyavor, Kafui
Egiebor, Nosa O
description An evaluation of the effect of differences in chromium nitrate to cement ratio on the microbial stability of a chromium nitrate/cement waste form, as reflected in the leaching of chromium, calcium, magnesium and aluminum; was carried out in this study. An increase in the proportion of chromium in the waste form from 4.8 to 8.7% had no noticeable effect on microbial stability, with the total chromium leached essentially unchanged. Further increases in the proportion of chromium in the waste form from 8.7 to 10.7%, and from 10.7 to 15.9% resulted in a substantial decrease in microbial stability, with 3-fold and 1.3-fold increase in the total chromium leached, respectively, observed. For calcium, increases in the chromium proportion were accompanied with increases in the total calcium leached even though the increases were not in direct proportion to the increases in chromium proportion. For magnesium and aluminum, increases in the proportion of chromium within the range 4.8–10.7% were accompanied with increases in the total respective metals leached, with minor variation for each metal. On the whole, the maximum percentage chromium leached from the different waste forms was substantially lower than those of the other metals.
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subjects Aluminum - analysis
Analysis methods
Applied sciences
Bacteria
Biodegradation of pollutants
Biological and medical sciences
Biotechnology
Calcium - analysis
Cement-based waste
Chromium - analysis
Chromium Compounds - chemistry
Diffusion
Environment and pollution
Environmental Pollution - prevention & control
Exact sciences and technology
Fundamental and applied biological sciences. Psychology
Industrial applications and implications. Economical aspects
Magnesium - analysis
Manufactured Materials
Microbial stability
Nitrates - chemistry
Pollution
Population Dynamics
Refuse Disposal
Soil Pollutants - analysis
Solubility
Waste stabilization/solidification
Wastes
title Microbial stability evaluation of cement-based waste forms at different waste to cement ratio
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