Dark-cure studies of cationic photopolymerizations of epoxides: Characterization of the active center lifetime and kinetic rate constants

We have characterized the effective rate constants for termination/trapping (kt/t) and propagation (kp) for solvent‐free cationic photopolymerizations of phenyl glycidyl ether for conversions up to 50%. We have performed dark‐cure experiments in which active centers are produced photochemically for...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2003-07, Vol.41 (13), p.2064-2072
Hauptverfasser:	Sipani, Vishal, Scranton, Alec B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences cationic polymerization Exact sciences and technology kinetics (polym.) photopolymerization Physicochemistry of polymers Polymerization Polymers and radiations
Online-Zugang:	Volltext
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